Synthesis and physico-chemical studies of a novel organo-metallic compound CdCl2(C6H4FNH2)2

Nasr, Mahjouba Ben; Aubert, Emmanuel; Espinosa, Enrique; Lefèbvre, F.; Nasr, C. Ben

doi:10.1016/j.molstruc.2014.10.075

Cited by 6 publications

(2 citation statements)

References 40 publications

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“…Examination of the organic geometrical features (Table 2) shows that the 4fluoroaniline molecule exhibits a regular spatial configuration with C-C and C-N distances and C-C-C and C-C-N angles quite similar to those found in other fluoroaniline compounds [37,40]. It is worth noticing that no -stacking interactions between neighboring aromatic rings are present in the structure, and only one C-H interaction towards them is observed.…”

Section: X-ray Diffraction Studymentioning

confidence: 65%

Crystal structure, Hirshfeld surface analysis, quantum mechanical study and spectroscopic characterization of the non-centrosymmetric coordination compound bis(4-fluoroaniline)dichloridozincate

Nasr¹,

Soudani²,

Lefèbvre

et al. 2017

Journal of Molecular Structure

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The Zn(II) complex with the monodentate ligand 4-fluoroaniline, ZnCl 2 (C 6 H 4 FNH 2) 2 , has been prepared and characterized by single crystal X-ray diffraction, solid state nuclear magnetic resonance, infrared spectroscopy and differential scanning calorimetry. The Zn(II) ion is tetracoordinated by two nitrogen atoms of two monodentate 4-fluoroaniline ligands and two chlorine atoms. In the molecular arrangement, the ZnCl 2 (C 6 H 4 FNH 2) 2 entities are interconnected via N-HCl hydrogen bonds to form layers parallel to the (a, b) plane. The nature and proportion of contacts in the crystal packing were investigated through the Hirshfeld surfaces. The crystal is mainly maintained by electrostatic attractions Cl-…H-N and by extensive hydrophobic contacts as revealed by the Hirshfeld 2D fingerprint plots and statistical analysis. The 13 C and 19 F CP-MAS NMR spectra are in agreement with the X-ray structure and confirm the phase purity of the crystalline sample. The vibrational absorption bands were identified by infrared spectroscopy. A calorimetric study shows that the title compound is stable until 262.5 °C.

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Section: X-ray Diffraction Studymentioning

confidence: 65%

Crystal structure, Hirshfeld surface analysis, quantum mechanical study and spectroscopic characterization of the non-centrosymmetric coordination compound bis(4-fluoroaniline)dichloridozincate

Nasr¹,

Soudani²,

Lefèbvre

et al. 2017

Journal of Molecular Structure

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“…Some of these compounds are interesting due to the possibility of possessing new properties and multifunctional character. Potential applications have been described for such diverse fields as catalysis, optics, electronics, medicine, conductivity and biology [1][2][3][4][5][6][7][8]. Zinc is well suited for the construction of a diversity of coordination compounds, as its d 10 electronic configuration allows a variety of coordination numbers and geometries which are not dependent on ligand-field stabilization but rather on ligand charge and size.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O

Basdouri

Trojette

Falvello

et al. 2019

Journal of Molecular Structure

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Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O. AbstractThe new organic-inorganic hybrid material [Zn(H2O)6][{(CH2)6N4}ZnCl3]2·0.5 H2O, is the second hydrate in this system, the first having been the hexahydrate. The new solid was prepared by slow evaporation of a solution of the reactants at room temperature and was structurally characterized by X-ray crystallography. This compound crystallizes in the trigonal system, space group P-3c1 with a = 9.8303(2)Å, c = 17.5460(2)Å, V = 1468.38(4)Å 3 and with Z = 2. The complex was characterized by FT-IR, thermogravimetric analysis (TGA), differential thermal analysis (DTA) and with a detailed analysis of Hirshfeld surfaces and fingerprint plots. The structural unit of the title compound consists of a [Zn II (H2O)6] 2+ cation, two [Zn II Cl3(hmt)]anions and half of a water molecule, partially occupied and disordered [hmt is hexamethylenetetramine, (CH2)6N4]. Crystal packing is mediated by O-H…N and O-H…Cl hydrogen bonds between the anions and cations, and to a lesser extent by O-H…O contacts, which are present only part of the time as a consequence of the partial occupancy of the isolated water molecules. The relationship between the packing in the new structure and that of the previous hexahydrate is described.

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Optical and electric properties of the organic-inorganic hybrid bis(2-amino-5-picolinium) Tetrachlorocobaltate(II) [(C6H9N2)2CoCl4]

Ghoudi,

Chaabane,

Naouari

et al. 2024

Inorganic Chemistry Communications

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Synthesis and physico-chemical studies of a novel organo-metallic compound CdCl2(C6H4FNH2)2

Cited by 6 publications

References 40 publications

Crystal structure, Hirshfeld surface analysis, quantum mechanical study and spectroscopic characterization of the non-centrosymmetric coordination compound bis(4-fluoroaniline)dichloridozincate

Crystal structure, Hirshfeld surface analysis, quantum mechanical study and spectroscopic characterization of the non-centrosymmetric coordination compound bis(4-fluoroaniline)dichloridozincate

Synthesis, crystal structure, infrared spectroscopy, thermal analysis and Hirshfeld surface analysis of a new hemihydrate of [Zn (H2O) 6][{(CH2)6N4}ZnCl3]2·0.5H2O

Optical and electric properties of the organic-inorganic hybrid bis(2-amino-5-picolinium) Tetrachlorocobaltate(II) [(C6H9N2)2CoCl4]

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