Synthesis and preparation of sulfonated hyperbranched poly(aryl ether ketone)–sulfonated linear poly(aryl ether ketone) blend membranes for proton exchange membranes

Wang, Hui; Pang, Jinhui; Zhou, Fugui; Zhang, Haibo; Jiang, Zhenhua; Zhang, Shuling

doi:10.1177/0954008313485103

Cited by 10 publications

(6 citation statements)

References 28 publications

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“…It has been reported that the ion mobility can be enhanced remarkably by the formation of connective localized ionic channels that are created by phase separation. 32 Therefore, the microphase-separated morphology would have a great influence on the properties of PEMs based on SAm-PEEK- x , such as proton conductivity, water sorption, and methanol permeability. This will be discussed in the following sections.…”

Section: Resultsmentioning

confidence: 99%

Poly(ether ether ketone) grafted with sulfoalkylamine as proton exchange membrane

Shao

Zhao

2018

High Performance Polymers

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A series of side-chain-type sulfonated poly(arylene ether ketone)s with high ion exchange capacity (IEC) values were prepared by polycondensation reaction of 4,4′-difluorobenzophenone with 2,2′-bis(3-amino-4-hydroxyphenyl) and bisphenol A, followed by post-grafting reaction using 1,4-butanesultone. For these obtained membranes, sulfoalkylamine functionalized poly(ether ether ketone) (SAm-PEEK)-0.8 with the highest IEC of 3.42 mequiv. g−1 displayed the highest proton conductivity of 0.11 S cm−1 at 25°C and 0.167 S cm−1 at 60°C, respectively. The morphology of these membranes was investigated by transmission electron microscope analysis. The result showed that these membranes exhibited well-connected hydrophilic channels due to their high IEC values and densely populated flexible acid side chains. Owing to their low methanol permeability and high selectivity, SAm-PEEK- x membranes are promising candidates for direct methanol fuel cell applications.

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Section: Resultsmentioning

confidence: 99%

Poly(ether ether ketone) grafted with sulfoalkylamine as proton exchange membrane

Shao

Zhao

2018

High Performance Polymers

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“…Wang et al [287] prepared sulfonated linear poly(aryl ether ketone) (S-LPAEK)/ sulfonated hb poly(aryl ether ketone)s (S-hb-PAEKs) blend membranes and focused on the influence of the IEC and the content of S-hb-PAEKs on the properties of the blend membranes. The S-LPAEK membranes with varying content of sulfonated groups were synthesized and characterized.…”

Section: Sulfonated Hb Poly(aryl Ether Ketone) For Pemfcmentioning

confidence: 99%

Aromatic Hyperbranched Polymers: Synthesis and Application

Ghosh

Banerjee

Voit

2014

Porous Carbons – Hyperbranched Polymers – Polymer Solvation

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Hyperbranched (hb) polymers have been receiving increasing attention because of their unique architecture that results in an interesting set of unusual chemical and physical properties. Over the past decade quite a number of excellent reviews on hb polymers have been published by different research groups, covering various aspects of this class of polymers. This review will highlight the work on aromatic hb polymers of the last decade, emphasizing general synthetic strategies and recent development of alternative synthetic strategies, and discussing various aspects of hb polymers to demonstrate their wide range of applications.

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“…Thus, aromatic hydrocarbon polymers are investigated as alternative PEM materials. [3][4][5][6][7][8] Among the aromatic hydrocarbon polymers, sulfonated poly(arylene ether)s (SPAEs) are considered as promising candidates for PEM materials because of their high thermochemical stability, high mechanical strength, good film-forming ability, and low fuel gas (or liquid) crossover. [9][10][11] Side-chain-style aromatic polymers have recently attracted attention.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and properties of poly(arylene ether nitrile) with pendant bisulfonic acid for proton exchange membrane application

Dong

Zhu

Song

et al. 2017

High Performance Polymers

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A new class of poly(arylene ether nitrile) with a bisulfonated phenyl ring on the side chains (PAEN-bS) was prepared from a hydroxybenyl-containing polymer precursor and a bisulfonated monomer by applying graft reaction. The polymers were soluble in common organic solvents such as dimethylsulfoxide (DMSO, purity>99.5%; Sinopharm Chemical Reagent Co., Ltd, Shanghai, China), N,N-dimethylacetamide (DMAc, purity>99.0%; Sinopharm Chemical Reagent Co., Ltd, Shanghai, China), dimethylformamide (DMF, purity>99.0%; Sinopharm Chemical Reagent Co., Ltd), and 1-methyl-2-pyrrolidinone (NMP, purity>99.0%; Sinopharm Chemical Reagent Co., Ltd) and showed good thermal stability, with a 5% weight loss and temperature higher than 320 C. Remarkably, all the PAEN-bS membranes showed a high proton conductivity of more than 10 À2 S cm À1 at room temperature and a low swelling ratio of less than 20% at 100 C; in particular, the conductivity of the PAEN-Bs-60 polymer membrane with the highest ion exchange capacity value was higher than that of Nafion 117 at all test temperature ranges. The combination of good thermal stability, excellent dimensional stability, and high proton conductivity indicates that these polymers are good candidate materials for proton exchange membranes in fuel cell applications.

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Synthesis and preparation of sulfonated hyperbranched poly(aryl ether ketone)–sulfonated linear poly(aryl ether ketone) blend membranes for proton exchange membranes

Cited by 10 publications

References 28 publications

Poly(ether ether ketone) grafted with sulfoalkylamine as proton exchange membrane

Poly(ether ether ketone) grafted with sulfoalkylamine as proton exchange membrane

Aromatic Hyperbranched Polymers: Synthesis and Application

Synthesis and properties of poly(arylene ether nitrile) with pendant bisulfonic acid for proton exchange membrane application

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