Abstract:A trinuclear copper(II) phthalocyanine complex was synthesized by chelate coordination of the peripherally introduced Schiff-base nitrogen and phenoxide oxygen on the Cu(pc) core to a copper(II) ion. The magnetic, spectral and electrochemical properties were compared with those of the precursor mononuclear Cu(pc) complex with the NO chelate coordination site and a mononuclear Schiff-base copper(II) complex corresponding to the central bis-chelated unit of the title trinuclear complex. A stronger aggregating na… Show more
“…Oximes are an important class of ligands due to their metal complexes, which have been widely studied and some studies on this subject are already available [4,5]. Recently much attention is being focused on analytical reagents for the detection and determination of some metal ions [6], nonlinear optical materials field [7] and supramolecular architectures [8][9][10][11][12] etc. The single crystal structure of the title complex was determined by X-ray crystallography.…”
“…Oximes are an important class of ligands due to their metal complexes, which have been widely studied and some studies on this subject are already available [4,5]. Recently much attention is being focused on analytical reagents for the detection and determination of some metal ions [6], nonlinear optical materials field [7] and supramolecular architectures [8][9][10][11][12] etc. The single crystal structure of the title complex was determined by X-ray crystallography.…”
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