Synthesis and properties of alkylvanadium(III) alkoxides

Razuvaev, G. A.; Vyshinskaya, L. I.; Дроботенко, В. В.; Mal'kova, G.Ya.; Vyshinsky, N.N.

doi:10.1016/s0022-328x(00)95259-8

Cited by 11 publications

(1 citation statement)

References 3 publications

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“…3 Several alkyl vanadium(III) alkoxide complexes like RV(O t Bu) 2 XMgO t Bu (X = Cl, Br) also insert carbon dioxide reversibly. 4 Molybdenum systems like Mo 2 (O i Pr) 4 (L) 4 (L = PMe 3 , HO i Pr) 5 react with carbon dioxide to give Mo 2 (O 2 CO i Pr) 4 and Mo 2 (O 2 CO i Pr) 4 (PMe) 4 . Copper(I) alkoxides of the type ROCu(PPh 3 ) 2 6 (R = C 2 H 5 , C 6 H 5 CH 2 ) react with carbon dioxide at low temperatures giving a complex of the formula ROC(O)OCu(PPh 3 ) 2 ; whereas when R is t Bu, in ROCuL n (L = PEt 3 , t BuNC) the insertion is reversible.…”

Section: Insertion Of Carbon Dioxide Into Titanium Isopropoxide Takes...mentioning

confidence: 99%

On the water promoted reaction of titanium isopropoxide with carbon dioxideElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b307217g/

2003

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Section: Insertion Of Carbon Dioxide Into Titanium Isopropoxide Takes...mentioning

confidence: 99%

On the water promoted reaction of titanium isopropoxide with carbon dioxideElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b307217g/

2003

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Kohlendioxid als alternativer C₁‐Baustein: Aktivierung durch Übergangsmetallkomplexe

Behr

1988

Angewandte Chemie

123

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Das Kohlendioxidmolekiil hat bislang nur eine geringe Bedeutung als Synthesebaustein in der Organischen Chemie. Uber seine Koordination an Ubergangsmetalle ergeben sich jedoch vollkommen neue Reaktionsmoglichkeiten: C 0 2 wird in vielfaltiger Weise an Metallkomplexen fixiert, kann stochiometrische Kupplungs-und Insertionsreaktionen eingehen sowie katalytisch mit anderen Substraten verkniipft werden. Insbesondere die homogenkatalytische C-C-Verknupfung von Kohlendioxid mit ungeslttigten Kohlenwasserstoffen eroffnet neue Wege zu technisch interessanten organischen Verbindungen.

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Carbon Dioxide as an Alternative C₁ Synthetic Unit: Activation by Transition‐Metal Complexes

Behr¹

1988

Angew. Chem. Int. Ed. Engl.

337

110

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The carbon dioxide molecule has been of limited importance as a synthetic unit in organic chemistry. When it is coordinated to transition metals, however, completely new possibilities arise; CO2 can bond to metal complexes in a variety of ways and can enter into insertion and coupling reactions, or become catalytically attached to other substrates. The formation of CC bonds between carbon dioxide and unsaturated hydrocarbons under conditions of homogeneous catalysis makes available new synthetic routes to industrially interesting organic compounds.

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Synthesis and properties of alkylvanadium(III) alkoxides

Cited by 11 publications

References 3 publications

On the water promoted reaction of titanium isopropoxide with carbon dioxideElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b307217g/

On the water promoted reaction of titanium isopropoxide with carbon dioxideElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b307217g/

Kohlendioxid als alternativer C₁‐Baustein: Aktivierung durch Übergangsmetallkomplexe

Carbon Dioxide as an Alternative C₁ Synthetic Unit: Activation by Transition‐Metal Complexes

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Synthesis and properties of alkylvanadium(III) alkoxides

Cited by 11 publications

References 3 publications

On the water promoted reaction of titanium isopropoxide with carbon dioxideElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b307217g/

On the water promoted reaction of titanium isopropoxide with carbon dioxideElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b307217g/

Kohlendioxid als alternativer C1‐Baustein: Aktivierung durch Übergangsmetallkomplexe

Carbon Dioxide as an Alternative C1 Synthetic Unit: Activation by Transition‐Metal Complexes

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Kohlendioxid als alternativer C₁‐Baustein: Aktivierung durch Übergangsmetallkomplexe

Carbon Dioxide as an Alternative C₁ Synthetic Unit: Activation by Transition‐Metal Complexes