1987
DOI: 10.1016/0379-6779(87)90898-8
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Synthesis and properties of electrically conducting polymers from aromatic amines

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Cited by 76 publications
(23 citation statements)
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“…From FTIR bands (Fig. 2a), it was found that polymerization occurs with head to tail coupling [43]. The 1160 and 1200 cm − 1 bands belong to the -N_Q_N or B-NH-B (where B denotes benzenoid and Q denotes quinoid ring) vibration bands of P2ClAn.…”
Section: Resultsmentioning
confidence: 98%
See 1 more Smart Citation
“…From FTIR bands (Fig. 2a), it was found that polymerization occurs with head to tail coupling [43]. The 1160 and 1200 cm − 1 bands belong to the -N_Q_N or B-NH-B (where B denotes benzenoid and Q denotes quinoid ring) vibration bands of P2ClAn.…”
Section: Resultsmentioning
confidence: 98%
“…The mobility value in conjugated polymers has been reported around 10 − 4 cm 2 V − 1 s − 1 and it is known to depend on the field [63]. Furthermore, such as in PANI [43][44][45], it could also be used Al/P2ClAn contacts with CH 3 COO − anion as switching or memory elements.…”
Section: Resultsmentioning
confidence: 99%
“…The band observed at 1169 cm −1 corresponds to two peaks not clearly separated: the C H stretch of the quinoid ring at 1163 cm −1 and the C H stretch of the benzoid ring band observed at 1178 cm −1 [18]. The band observed at 1590 cm −1 can be ascribed to the stretching mode of the C C bond in the quinoid ring with a small shoulder at 1603 cm −1 assigned to the stretching mode of the benzoid ring (C C bond) observed at 1610 cm −1 [20,21].…”
Section: In Situ Raman Spectroscopy Of Pan/co-poly Coated Ptmentioning
confidence: 86%
“…It is formed as a result of strictly regular assembly of monomer units. The chain of conducting PANI contains more than 95% of para-substituted aniline fragments linked in a "head-to-tail" configuration (Hagiwara et al 1987). Defects in this regular structure arising during copolymerization of aniline with other monomers or after introduction of aniline units with another configuration (ortho-or meta-substituted fragments) lead to dramatic decrease in conductivity.…”
Section: Polyaniline: Structure Forms and Their Propertiesmentioning
confidence: 99%