1996
DOI: 10.1016/s0379-6779(96)03783-6
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Synthesis and properties of oligothiophene cation radical salts

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Cited by 11 publications
(4 citation statements)
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“…Oligothiophenes with long conjugation lengths, for example, 16-, 20-, and 27-mers, are expected to serve as molecular wires. In addition, cyclic oligothiophenes and selenium analogues of oligothiophenes , have also been synthesized. Although oligothiophenes are highly crystalline, amorphous molecular materials containing oligothiophenes have been designed and synthesized. There have been extensive studies on the molecular and crystal structures, and optical, electrochemical, and electrical properties of oligothiophenes and their applications in OPVs, OLEDs, and OFETs. …”
Section: 2 Crystalline Molecular Materials421 Representative Classes ...mentioning
confidence: 99%
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“…Oligothiophenes with long conjugation lengths, for example, 16-, 20-, and 27-mers, are expected to serve as molecular wires. In addition, cyclic oligothiophenes and selenium analogues of oligothiophenes , have also been synthesized. Although oligothiophenes are highly crystalline, amorphous molecular materials containing oligothiophenes have been designed and synthesized. There have been extensive studies on the molecular and crystal structures, and optical, electrochemical, and electrical properties of oligothiophenes and their applications in OPVs, OLEDs, and OFETs. …”
Section: 2 Crystalline Molecular Materials421 Representative Classes ...mentioning
confidence: 99%
“…Although oligothiophenes are highly crystalline, amorphous molecular materials containing oligothiophenes have been designed and synthesized. [60][61][62][63] There have been extensive studies on the molecular and crystal structures, and optical, electrochemical, and electrical properties of oligothiophenes [64][65][66][67][68][69][70][71][72][73][74][75][76] and their applications in OPVs, 77 OLEDs, and OFETs. [78][79][80][81] Some crystalline materials, for example, polycyclic aromatic hydrocarbons and phthalocyanines, form thin films with amorphous nature by vacuum deposition on substrates kept at moderate to low temperatures.…”
Section: Representative Classes Of Crystalline Materialsmentioning
confidence: 99%
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“…In addition to enhanced chemical stability, end-substitution does not induce inter-ring torsion (as often does side-substitution) thus retaining high p-conjugation and electroactivity. Hotta and Waragai have applied this strategy to a-4T and investigated the crystal structure of a-4T(a-Me) 2 (Scheme 3) in its neutral form 25,44 while its doped form was studied by Matsuura et al 65 In contrast to non-substituted a-oligothiophenes, crystals of neutral a-4T(a-Me) 2 are orthorhombic with a Pbca space group and Z~4. The molecules are almost coplanar, the two outer rings being slightly bent according to the mean plane of the two inner ones (maximum deviation is ca.…”
Section: Introductionmentioning
confidence: 99%