“…It was seen that treating PVC surface in plasma led to the C–C, C–Cl, and C–H bonds scission since the induced energy exceeded the bonds dissociation energy [43,44,45,46,47,48,49,50,51,52,53]. Plasma exposure in an inert gas gave rise to the generation of metastable species, that is, carbon radicals (Figure 1) on PVC surfaces which could either form a crosslinked network or be oxidized to give new functionalities, in case the treated surface was exposed to air [43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58]. Provided oxygen or air was operated as the working gas, carbonyl, carboxyl, peroxide, and ester groups were most probable to form [59].…”