Synthesis and Properties of Some Simple Organotitanium Compounds

Reetz, Manfred T.

doi:10.1007/978-3-642-70704-9_2

Reactivity and Structure: Concepts in Organic Chemistry

1986

DOI: 10.1007/978-3-642-70704-9_2

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Synthesis and Properties of Some Simple Organotitanium Compounds

Manfred T. Reetz

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Cited by 2 publications

References 266 publications

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The Facile Synthesis of Lithium 2‐R‐Hydroquinolinide Complexes and Their High Activity toward ROP of ε‐Caprolactone

Fan

Wang

et al. 2020

Eur J Inorg Chem

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Four lithium 2-R-hydroquinolinide complexes [1-(2-(R)-C 9 H 7 )NLi·THF 2 ] 2 (1 R = Me, 2 R = nBu) and [1-(8-(Me)-2-(Bu n )-C 9 H 6 )NLi·X] 2 (3 X = THF, 4 X = Et 2 O) were prepared by the nucleophilic addition reaction of quinoline and 8-methylquinoline with MeLi or Bu n Li, respectively. All complexes have been characterized through NMR spectroscopy. Complexes 2-4 were determined by X-ray crystallography. Interestingly, Li atom in 1 and 2 is tetracoordinate, whereas Li atom in 3 and 4 is threecoordinate. All these complexes showed super-high activity for [a]

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The Facile Synthesis of Lithium 2‐R‐Hydroquinolinide Complexes and Their High Activity toward ROP of ε‐Caprolactone

Fan

Wang

et al. 2020

Eur J Inorg Chem

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Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Alkyltitanium Alkoxides with Aryl and Alkenyl Halides

2022

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Here, we report that alkyltitanium alkoxides generated in situ from Grignard reagents and Ti(OiPr)4 undergo a photocatalyst-free nickel-catalyzed cross-coupling with organic halides upon irradiation with blue light. Mechanistic studies suggested that the reaction proceeds through radical intermediates formed by photochemical decomposition of the alkyltitanium reagents. Various aryl, heteroaryl, and vinyl halides were efficiently alkylated under the reported conditions, including those containing ester and amide groups.

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Synthesis and Properties of Some Simple Organotitanium Compounds

Cited by 2 publications

References 266 publications

The Facile Synthesis of Lithium 2‐R‐Hydroquinolinide Complexes and Their High Activity toward ROP of ε‐Caprolactone

The Facile Synthesis of Lithium 2‐R‐Hydroquinolinide Complexes and Their High Activity toward ROP of ε‐Caprolactone

Visible-Light-Promoted Nickel-Catalyzed Cross-Coupling of Alkyltitanium Alkoxides with Aryl and Alkenyl Halides

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