Synthesis and Properties of Two Amino Carboxylic Acid Gemini Surfactants

Abstract

The number of hydrophilic and hydrophobic groups of a surfactant has a great influence on its property. Two Gemini surfactants, N,N 00 '-didodecyl-N,N',N 00 ,N 00 'tetrapropionate triethylenetetramine and N,N'-didodecyl-N, N'-dipropionate ethylenediamine (referred as DTPTT and DDPED), were prepared by Michael addition reaction of the didodecyl secondary amines with methyl acrylate. The didodecyl secondary amines were synthesized by nucleophilic substitution reaction of triethylenetetramine or ethylenediamine with bromododecane. The DTPTT and DDPED surfactants were characterized by mass spectrometry and proton nuclear magnetic resonance spectrometry. The surface activities of the DTPTT and DDPED aqueous solutions were studied by surface tension measurements. The surface tension and critical micelle concentration (cmc) of DDPED is smaller than that of DTPTT. The DDPED can reduce the surface tension of water to approximate 34 mN m −1 at concentration levels of 10 −5 mol L −1. The aggregation behavior of the DTPTT and DDPED aqueous solution were studied by dynamic light scattering and transmission electron microscopy. Both surfactants can form spherical vesicles at a solution of about 3-5 times cmc of the Gemini surfactants. The foam property was determined by nitrogen blowing method. The DTPTT has relatively good foaming ability and DDPED has excellent foam stability. The foam volume of DDPED barely change within 1000s. The emulsion stability of the Gemini surfactants was determined by separation time of water from the emulsion. The emulsion stability of DDPED is equivalent to Tween 80. The DDPED Gemini surfactant with two hydrophilic carboxylic groups has better surface activity, foam stability, and can be used as an O/W emulsifier.

Froth stability and entrainment evaluation of a novel frother for KCl/NaCl flotation

“…Improvements in frother performance are mainly achieved by surfactant mixing, gemini surfactants, or surfactants with high bubble performance 18–20 . However, the implementation of surfactant mixing in real flotation is quite challenging because extensive experiments are required.…”

“…[12][13][14][15][16][17] Improvements in frother performance are mainly achieved by surfactant mixing, gemini surfactants, or surfactants with high bubble performance. [18][19][20] However, the implementation of surfactant mixing in real flotation is quite challenging because extensive experiments are required. Hulya 18 used several mixture frothers (i.e., pine oil + MIBC, pine oil + Aerofroth 88 (2-ethylhexanol; C 8 H 18 O), MIBC + Aerofroth 88) to evaluate the flotation performance of artificial ore (celestite/calcite, 1:1).…”