Synthesis and protection: a controllable electrochemical approach to polypyrrole-coated copper azide with superior safety for MEMS

Bao, Minghao; Yu, Chunpei; Yang, Gexing; Chen, Junhong; Cheng, He; Xu, Jianyong; Shi, Wei; Song, Changkun; Lei, Xiaoting; Han, Zhongbo; Zhang, Wenchao

doi:10.1039/d3lc00986f

Lab Chip

2024

DOI: 10.1039/d3lc00986f

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Synthesis and protection: a controllable electrochemical approach to polypyrrole-coated copper azide with superior safety for MEMS

Minghao Bao,

Chunpei Yu,

Gexing Yang

et al.

Abstract: Traditional lead-based primary explosives present challenges in application to micro-energetics-on-a-chip. It is highly desired but still remains challenging to design a primary explosive for the development of powerful yet safe...

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Lithium Ion Promoted the Formation of a Heat-Resistant Energetic Metal Salt with Dinitromethyl Functional Groups

Wang,

Yang,

Cheng

et al. 2024

Crystal Growth & Design

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Heat-resistant explosives are indispensable compounds in the fields of energy exploitation and aviation. In this study, with 5-nitro-3-trinitromethyl-1,2,4-triazole as the raw material, an energetic metal salt dilithium 5-nitro-3-(dinitromethyl)-1,2,4-triazole (DN-2Li) with high thermal stability was obtained. The application evaluation parameters including thermal stability, mechanical sensitivity, and detonation performance were fully studied. The results show that DN-2Li not only has good detonation performance (D v = 8669 m s −1 , P = 30.2 GPa) but also has appropriate mechanical sensitivity (IS = 4.0 J, FS = 100 N) and excellent thermal stability (T d = 350.0 °C, E K = 235.1 kJ mol −1 ), which fully implies that DN-2Li has high application value as a heat-resistant explosive. This study not only provides a kind of heat-resistant explosive with potential application value but also provides a new vision for the design and preparation of new heat-resistant explosives.

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Lithium Ion Promoted the Formation of a Heat-Resistant Energetic Metal Salt with Dinitromethyl Functional Groups

Wang,

Yang,

Cheng

et al. 2024

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

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Synthesis and protection: a controllable electrochemical approach to polypyrrole-coated copper azide with superior safety for MEMS

Abstract: Traditional lead-based primary explosives present challenges in application to micro-energetics-on-a-chip. It is highly desired but still remains challenging to design a primary explosive for the development of powerful yet safe...

Cited by 1 publication

References 37 publications

Lithium Ion Promoted the Formation of a Heat-Resistant Energetic Metal Salt with Dinitromethyl Functional Groups

Lithium Ion Promoted the Formation of a Heat-Resistant Energetic Metal Salt with Dinitromethyl Functional Groups

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