“…The peaks are asymmetric and more broadening, and three modes including E 2 (low), A 1 (TO) and A 1 (LO) are large red-shift compared with the peaks from the wurtzite GaN bulk and epitaxial film data [27]. It is thought that the red-shift of these modes results from the size confinement effects and internal stress [28][29][30]. An interesting phenomenon is that four additional modes are also observed at 230.4, 422.6, 839.1 and 968.2 cm −1 , respectively, which is not allowed by the wurtzite-type structure.…”