Synthesis and reactions of cationic rhodium nitrosyl complexes

Synthesis, characterization and reactivity of tribenzylphosphine rhodium and iridium complexes

“…A similar Rh(I) complex with PPh 3 has been synthesized from cationic rhodium-nitrosyl species and shows similar IR features [44]. Also, a tricarbonyl iridium species with P(p-CH 3 C 6 H 4 ) 3 was reported, and the presence of three carbonyls sitting in the equatorial plane of a trigonal-bipyramidal polyhedron was confirmed by the presence of a unique m COband (2010 cm À1 ) [35].…”

Protonation of cobalt, rhodium, and iridium hydrides with fluorocarbon acids. Synthesis, reactivity, and dynamic properties of tris(triphenylphosphine)rhodium(1+) and its derivatives

“…The [(Ph3P)2Rh(CO)2]+ cation has been reported to form upon reaction of [(Ph3P)2Rh(NO)(CH3CN)2] [PF6]2 with CO at 10 atm pressure, but no characterization data are available. 31 Here, the composition and stereochemistry in 17 are defined by the A2MX2 NMR spectra (A = 13C, M = 103Rh, and X = 31P) of the Relabeled analogue, prepared by exchange of 17 with 13CO. At <-60 °C, the l3C NMR spectrum of 17 in CD2C12 reveals a doublet of triplets centered at 185.4 ppm with JCP = 14.8 Hz and JCRtl = 66 Hz.…”

Synthesis and reactivity of cationic pentacoordinate nitrosyl complexes

“…Connelly et al using a different procedure. 10 Our method seems to be generally applicable for the synthesis of cationic nitrosyl complexes containing both phosphine and two molecules of coordinating solvent in which the reaction is carried out.…”