Synthesis and reactivity of alkali metal aluminates bearing bis(organoamido)phosphane ligand

Abstract

In this work, we report a group of alkali metal aluminates bearing bis(organoamido)phosphane ligand. The starting complex {[PhP(NtBu)2]AlMe2}Li.OEt2 (1) was prepared by a stepwise deprotonation of the parent PhP(NHtBu)2 by...