Synthesis and Reactivity of Aluminum Disilacyclopropenes. Cyclic AlSi<sub>2</sub> Delocalized 2π Systems

Guo, Lulu; Zhang, Jianying; Cui, Chunming

doi:10.1021/jacs.3c09358

J. Am. Chem. Soc.

2023

DOI: 10.1021/jacs.3c09358

|View full text |Cite

Synthesis and Reactivity of Aluminum Disilacyclopropenes. Cyclic AlSi₂ Delocalized 2π Systems

Lulu Guo,

Jianying Zhang,

Chunming Cui

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 64 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

Feng,

Yamashita

2024

J. Am. Chem. Soc.

View full text Add to dashboard Cite

The molecular chemistry of metal−metal bonds is crucial for understanding the bonding and reactivity of metalcontaining molecules as well as solid metals and their alloys, especially with respect to their application as catalysts for organic transformations and industrial processes. Despite the high efficiency of the recently developed nucleophilic alumanyl anions in the synthesis of diverse Al−metal bonds, the bonding between main group metals in a low oxidation state and the Al atom remains largely unexplored. This paper describes the reaction of an alumanyl anion with a chlorostannylene precursor to afford a compound with an unprecedented covalent Al−Sn bond. The lability of the covalent Al−Sn bond renders it reactive toward the insertion of carbodiimide, N 2 O, and phenylacetylene. Remarkably, the reaction with benzonitrile furnished an unprecedented Al,N-heteroallene species that contains a linear Al�N�C linkage.

show abstract

Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

Feng,

Yamashita

2024

J. Am. Chem. Soc.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis and Reactivity of Aluminum Disilacyclopropenes. Cyclic AlSi₂ Delocalized 2π Systems

Cited by 1 publication

References 64 publications

Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

Contact Info

Product

Resources

About

Synthesis and Reactivity of Aluminum Disilacyclopropenes. Cyclic AlSi2 Delocalized 2π Systems

Cited by 1 publication

References 64 publications

Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

Synthesis and Reactivity of an Alumanyl–Tin Species to Form an Al,N-Heteroallene Derivative

Contact Info

Product

Resources

About

Synthesis and Reactivity of Aluminum Disilacyclopropenes. Cyclic AlSi₂ Delocalized 2π Systems