Synthesis and Reactivity of Oxametallacyclic Niobium Compounds by Using α,β‐Unsaturated Carbonyl Ligands

Arteaga-Müller, Rocío; Sánchez‐Nieves, Javier; Royo, Pascual; Mosquera, Marta E. G.

doi:10.1002/ejic.200800060

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Synthesis Of Cationic Compounds1

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2010

2022

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Cited by 6 publications

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“…In all these compounds, the Lewis acid E(C 6 F 5 ) 3 (E ¼ B, Al) abstracted the Me group, also in the presence of an oxygen atom bound to the niobium atom, in contrast with the behaviour observed in oxametallacyclic niobium compounds [54]. H 3 ) aryloxo ligand of compound 2c might be the reason for the higher stability of the active species, favoring the polymerization process [42].…”

Section: Synthesis Of Cationic Compoundsmentioning

confidence: 91%