Synthesis and repellent properties of vinylidene fluoride-containing polyacrylates

Recent developments in polymeric superoleophobic surfaces

“…46,51,104 Gao et al 105 and Huang et al 106 synthesized a series of POSS-based hybrid terpolymers and fluorinated polyacrylates; after a dip-coating process, various superoleophobic fabrics were obtained. Hsieh et al investigated a one-step fabrication of fluoro-containing silica coatings on wooden substrates.…”

“…The optical transmittance of the surface is higher than 90%. 118 Super Oil-Repellent Coatings The broadest application for superoleophobic surfaces is constructing super oil-repellent coatings for textiles, 46,82,89,90,105,106,[119][120][121][122] woods, 107 metal, 53,104,123 and other substrates. 83,88 Oil-repellent coatings can keep substrates from fouling or corrosion by oils and other liquids, and thus show great significance.…”

Fluorinated pyridinium and ammonium cationic surfactants

“…In the case of fluoroalkyl chains interrupted with methylene groups, the thermal or redox-initiated insertion of vinylidene fluoride (VDF) into fluoroalkyl iodide bonds has been studied extensively by Ameduri and others [25][26][27][28][29]. Here a metalmeditated vinylidene fluoride Insertion of fluoroiodide, followed by radicalmediated ethylene insertion is employed [24].…”

Synthesis and water/oil repellency properties of cationic perfluoralkyl acrylate copolymer latices

“…The fluorine-containing compounds are used as, for example, the water-and oil-repellent agents and soil release agent by utilizing the properties. The fluorine-containing compounds have low free energy, excellent inertness to solvents, hydrocarbons, acids, alkalis and moisture adsorption can be considered as the advantages due to the low polarizability and the strong electronegativity of the fluorine atom [6][7][8][9][10][11]. Consequently, the fluorine-containing polymers have a wide-range of applications in modern industry [6,11], especially as surface coating agents for textile, paper and leather [1,8,10,[13][14][15].…”

“…Therefore, the investigations on fluorine-containing polymers emulsion, especially on fluorine-containing (meth)acrylate emulsion have attracted many researchers. There are various approaches for preparing fluorine-containing (meth)acrylate emulsion, such as the traditional emulsion polymerization [1,2,7,8,13,14,[17][18][19][20], the seeded emulsion polymerization, core-shell emulsion polymerization [10,12,[21][22][23][24][25], and miniemulsion copolymerizations [26].…”