Synthesis and rotational dynamics of diazamacrocycles having bridged 1,4-naphthylene as framed molecular rotors

Kurimoto, Taichi; Inagaki, Yusuke; Ohara, Kazuaki; Yamaguchi, Kentaro; Setaka, Wataru

doi:10.1039/d2ob01613c

Org. Biomol. Chem.

2022

DOI: 10.1039/d2ob01613c

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Synthesis and rotational dynamics of diazamacrocycles having bridged 1,4-naphthylene as framed molecular rotors

Taichi Kurimoto

Yusuke Inagaki

Kazuaki Ohara

et al.

Abstract: The rotation of a part of a molecule has attracted attention because of its possible role in the development of an artificial molecular rotor. In this study, 1,4-naphthylene bridged diazamacrocycles,...

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Topological Structural Chemistry of Fused Bicycloalkanes Allowing Homeomorphic Conversions

Setaka

2024

Eur J Org Chem

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Fused bicycloalkanes have several structures with different orientation of the substituents, such as out,out‐, in,in, and in,out‐structures. Some bicycloalkanes can undergo homeomorphic conversion between certain structures, for instance an out,out‐structure convert to an in,in‐structure. This homeomorphism can be achieved by one chain passing through the macroring. In this report, topological structural chemistry of fused bicycloalkanes and their analogues allowing homeomorphic conversions were reviewed. Although the concept of homeomorphism in fused bicycloalkanes was proposed 50 years ago, comprehensive researches on their structural chemistry are still ongoing. These understandings are highly relevant to the fundamentals of many fields of chemistry, including structural chemistry, theoretical chemistry, natural products chemistry, and materials science.

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Topological Structural Chemistry of Fused Bicycloalkanes Allowing Homeomorphic Conversions

Setaka

2024

Eur J Org Chem

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Synthesis and rotational dynamics of diazamacrocycles having bridged 1,4-naphthylene as framed molecular rotors

Abstract: The rotation of a part of a molecule has attracted attention because of its possible role in the development of an artificial molecular rotor. In this study, 1,4-naphthylene bridged diazamacrocycles,...

Cited by 1 publication

References 32 publications

Topological Structural Chemistry of Fused Bicycloalkanes Allowing Homeomorphic Conversions

Topological Structural Chemistry of Fused Bicycloalkanes Allowing Homeomorphic Conversions

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