Synthesis and size control of copper nanoparticles and their catalytic application

Jain, Shikha; Jain, Ankita; Kachhawah, Pranav; Devra, Vijay

doi:10.1016/s1003-6326(15)64048-1

Cited by 79 publications

(33 citation statements)

References 25 publications

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“…[18] In wet chemical method, reduction with ascorbic acid attracted chemist a lot. [19][20][21][22][23][24] The simple preparation procedure, usage of low cost chemicals and stability of NPs over a time are inspired to develop biosynthetic method for production of CuNPs with the help of lemon juice [25] from CuSO 4 .5H 2 O. The Lemon, Citrus limon (L.) Osbeck has rich amount of vitamin-C (ascorbic acid).…”

Section: Introductionmentioning

confidence: 99%

Biosynthesis of Copper Nanoparticles Supported on Zeolite Y and its Application in Catalytic C‐N Cross Coupling Reactions between Amines and Aryl halides

Raiza

Pandian

Kumar³

2019

ChemistrySelect

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A biosynthesis of Copper Nanoparticles supported on Zeolite Y and its application as efficient, reusable, heterogeneous catalyst in C−N cross coupling reactions between amines and aryl halides are reported. The biosynthesis of CuNPs/Zeolite Y was achieved by the reduction of CuSO4.5H2O with the lemon juice (without peal) and encapsulated into the Zeolite Y in a single step. In this biosynthetic method, the ascorbic acid present in the lemon juice acted as a reducing agent for CuSO4.5H2O. The CuNPs/Zeolite Y was characterized using UV‐Vis, powder XRD, FT‐IR, HR SEM, EDS and TGA. The average size of the CuNPs are found to be 50 nm and has large surface area for the efficient catalysis. The new catalyst is effect in catalyzing the C−N cross coupling reaction between amines and aryl halides (yield ranging from 89% to 95% depends on amine and aryl halide used). The catalyst can be recovered from the reaction mixture by simple procedure. The recovered catalyst is found to be active in catalyzing the coupling reaction even after five runs.

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Section: Introductionmentioning

confidence: 99%

Biosynthesis of Copper Nanoparticles Supported on Zeolite Y and its Application in Catalytic C‐N Cross Coupling Reactions between Amines and Aryl halides

Raiza

Pandian

Kumar³

2019

ChemistrySelect

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“…These nanomaterials are significant for possessing improved properties different from bulk materials simply by virtue of their small size, larger surface to volume ratio, distribution and morphology. Nanomaterials are of varied types such as metallic, insulating, semiconducting, and hybrid type [5][6][7]. Among the various kinds of nanomaterials, bio-synthesized metallic nanoparticles is increasing commercial demand for their unique properties such as physical, catalytic, chemical, electrical, electronic and antibacterial properties.…”

Section: Introductionmentioning

confidence: 99%

“…In nanotechnology, various methods are known to prepare nanoparticles with controlled size and shape. These include metal vapor deposition, radiolytic reduction, thermal decomposition, thermal reduction [4,5], electrochemical reduction [7], mechano-chemical process [8], chemical reduction etc. [7][8][9][10].…”

Section: Introductionmentioning

confidence: 99%

Bio-Synthesis of copper nanoparticles (CuNPs) using Garlic extract to investigate antibacterial activity

Amatya

Joshi

2020

BIBECHANA

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Bio-synthesis of metal nanoparticles (CuNPs) is regarded as one of the recently developed, economic and environmentally benign method. In the present investigation, Copper nanoparticles were synthesized reacting garlic (Allium sativum) extract with Copper Sulphate (CuSO4∙5H2O) solution over magnetic stirrer at 80 °C for 1 hour. So-prepared CuNPs were studied by observing the color change at various time intervals. Further, the nanoparticles were characterized using UV-Visible spectroscopy, Energy Dispersive X-ray spectroscopy (EDX) and Fourier Transform Infrared spectroscopy (FTIR). The results of UV-Vis spectroscopy clearly showed presence of absorption peak at 595 nm which confirmed the formation of copper nanoparticles. Likewise, the EDX spectrum depicts the presence of optical band at 8 eV which is the characteristic peak of Copper consisting of 38.747 % by weight and FTIR spectra revealed presence of various phytochemicals possessing characteristic functional groups such as carbonyl and phenolic at the surface of CuNPs. Thus, natural products available in the garlic extract help in reduction and stabilization of Copper nanoparticles. The antibacterial activity of Copper nanoparticles was investigated against Gram +ve (Staphylococcus aureus) and Gram –ve bacteria (Escherichia coli) using Agarwell diffusion method. The results of antibacterial test showed that CuNPs were found to be much sensitive towards Gram –ve bacteria compared to gram +ve bacteria. BIBECHANA 17 (2020) 12-18

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“…Jain et al . have addressed the synthesis of Cu(0) nanoparticles using ascorbic acid with copper chloride as a precursor; however, the methodology used high temperature (353 K) and long reaction time (24 h) for the reaction . Umer et al .…”

Section: Introductionmentioning

confidence: 99%

“…[19] Jain et al have addressed the synthesis of Cu(0) nanoparticles using ascorbic acid with copper chloride as a precursor; however, the methodology used high temperature (353 K) and long reaction time (24 h) for the reaction. [20] Umer et al have summarized the synthesis of Cu nanoparticles by heating the reaction mixture at 90 o C for longer time (17 h). [21] Khan et al have demonstrated the Cu-Cu 2 O type of composite nanomaterials using ascorbic acid by chemical reduction method; however the protocol used high temperature (80 o C) and long reaction time (2 h).…”

Section: Introductionmentioning

confidence: 99%

Room Temperature Synthesis of Copper Oxide Nanoparticles: Morphological Evaluation and Their Catalytic Applications for Degradation of Dyes and C–N Bond Formation Reaction

2016

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Synthesis of copper oxide (Cu2O and CuO) nanoparticles in different morphologies by a facile and cost effective method has been developed at room temperature. The effect of various copper precursors on the morphology of Cu2O nanoparticles has been addressed and achieved the 100 % uniform cubic morphology of Cu2O nanoparticles. The effect of different capping agents and bases also examined and selectively achieved rod, wire, belt like morphologies of CuO nanoparticles. The each capping agent plays the important role and responsible in building the morphology of copper oxide nanoparticles. Notably the synthesis procedure is simple, faster, economical and energy efficient as compared to the other existing methods with selectivity in morphology of copper oxide nanoparticles. In addition, we have shown the catalytic applications of synthesized Cu2O nanoparticles for the degradation of various dyes like methylene blue, methyl red and crystal violet and also as an efficient catalyst for C–N bond formation coupling reaction.

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Synthesis and size control of copper nanoparticles and their catalytic application

Cited by 79 publications

References 25 publications

Biosynthesis of Copper Nanoparticles Supported on Zeolite Y and its Application in Catalytic C‐N Cross Coupling Reactions between Amines and Aryl halides

Biosynthesis of Copper Nanoparticles Supported on Zeolite Y and its Application in Catalytic C‐N Cross Coupling Reactions between Amines and Aryl halides

Bio-Synthesis of copper nanoparticles (CuNPs) using Garlic extract to investigate antibacterial activity

Room Temperature Synthesis of Copper Oxide Nanoparticles: Morphological Evaluation and Their Catalytic Applications for Degradation of Dyes and C–N Bond Formation Reaction

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