Synthesis and spectral studies of diorganotin heterocyclic dithiocarbamate complexes: The crystal structure of (CH3)2Sn[(S2CH2]2

Synthetic, spectral, thermal and antimicrobial studies on some mixed 1,3-dithia-2-stannacyclopentane derivatives with dialkyldithiocarbamates

“…The infrared spectra of all these compounds have been recorded as KBr disc in the range 4000-200 cm À1 and tentative assignments of the important characteristic bands have been made with the help of earlier publications [8][9][10][11][12][13][14][15][16][17][18][19].…”

“…Most of the publications are restricted only on synthesis and characterization of tin(IV) and organotin(IV) derivatives with sulphur ligands like dithiolates [6,7] and dialkyldithiocarbamates [8][9][10][11][12][13][14][15][16][17][18][19]. A large number of diorganotin(IV) dialkyldithiocarbamate derivatives have been known including X-ray crystal structures of [Ph(Bu)Sn(S 2 CNEt 2 )Cl] [11], [R 2 Sn(S 2 CNMe 2 ) 2 ] [ etc.…”

Synthesis, Characterization and Biological Activities of Organotin (IV) Methylcyclohexyldithiocarbamate Compounds

“…In compound 1, the dithiocarbamate legends were bidentically chelated to the tin atom with one longer [Sn(1)-S(2) = 2.9785 (6) (Sharma et al,199). The long Sn-S distances were significantly less than the sum of the van der Waal's radii (4.0 Å) (Sharma et al, 1996). Compound 1 had a crystallographic mirror plane, coinciding with the C9/Sn1/C10 plane.…”

Diorganosilicon(iv) Complexes of Heterocyclic Dithiocarbamates. Synthesis and Structural Elucidations

“…Heterocyclic dithiocarbamates constitute an important class of sulphur donor ligands which show pronounced biological activities [9][10][11], In continuation to our work on heterocyclic dithiocarbamates of group IV organometallics [12][13][14], we report the synthesis and characterization of diorganosilicon derivatives of these ligands. 22, No.…”