2009
DOI: 10.1016/j.saa.2008.07.002
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Synthesis and spectroscopic studies on complexes of N,N’-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene (L); DNA binding studies on Cu(II) complex

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Cited by 34 publications
(11 citation statements)
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“…The observed magnetic moment of Cu(II) complex is 1.73 B.M. and it indicates an octahedral geometry [29][30][31][32]. Thus the electronic spectral data and magnetic moment data support the octahedral geometry of the complexes.…”
Section: Contents Lists Available At Sciencedirectmentioning
confidence: 74%
“…The observed magnetic moment of Cu(II) complex is 1.73 B.M. and it indicates an octahedral geometry [29][30][31][32]. Thus the electronic spectral data and magnetic moment data support the octahedral geometry of the complexes.…”
Section: Contents Lists Available At Sciencedirectmentioning
confidence: 74%
“…The lack of splitting of these bands suggests that the perchlorate anions are not coordinated [19]. The complex (2) shows bands at 1,492 cm -1 (m 1 ), 1,356 cm -1 (m 5 ), 1,211 cm -1 (m 2 ), and 826 cm -1 (m 6 ) indicating coordination of the nitrate groups [21,22]. The separation of *136 cm -1 between m 1 and m 5 indicates unidentate coordination of the nitrate [21].…”
Section: Resultsmentioning
confidence: 99%
“…The complex (2) shows bands at 1,492 cm -1 (m 1 ), 1,356 cm -1 (m 5 ), 1,211 cm -1 (m 2 ), and 826 cm -1 (m 6 ) indicating coordination of the nitrate groups [21,22]. The separation of *136 cm -1 between m 1 and m 5 indicates unidentate coordination of the nitrate [21]. The molar conductivity data at room temperature show that complex (1) is a 1:2 electrolyte, while complex (2) shows non-electrolytic nature [23].…”
Section: Resultsmentioning
confidence: 99%
“…The magnitude of spectral perturbation is an evidence for binding of the metal complexes to DNA helix [12]. [34]. Additionally, the red-shift observed is an evidence of the stabilization of the CT-DNA duplex.…”
Section: Electronic Absorption Spectramentioning
confidence: 99%