Synthesis and structural characterisation of gallium and indium fluoroalkoxide ‘ate’ complexes

Andrews, Philip C.; Forsyth, Craig M.; Junk, Peter Courtney; Nuzhnaya, Iryna; Spiccia, Leone

doi:10.1016/j.jorganchem.2008.11.002

Cited by 7 publications

(2 citation statements)

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“…95 The dinuclear gallium–lithium structure has previously been reported for [GaLi(MTB) 2 (THF) 3 ] where MTB = 2-oxo-2′-mercapto-1,1′-binaphthyl, 96 and [GaLi(OR) 4 (THF) 2 ] where RO = 2-trifluoromethyl-2-propanolato. 97 Heterometallic gallium–lithium alkoxides/aryloxides usually form tetranuclear clusters, i.e. [GaLi 3 (binol) 3 (THF) 4 ], [GaLi 3 (binol) 3 (DME) 3 ], 98 or [Me 2 GaLi(OR) 2 ] 2 for RO = 2-methoxyethanolato.…”

Section: Resultsmentioning

confidence: 99%

Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials

et al. 2022

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Section: Resultsmentioning

confidence: 99%

Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials

et al. 2022

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“…The crystal structures of several isostructural [M(hfip) 6 ] n – anions were published: [In(hfip) 6 ] 3– , [Ce(hfip) 6 ] 2– , and [Zr(hfip) 6 ] 2– 37–40. The sodium salt [Na 2 (C 6 H 6 ) 2 ][Zr(hfip) 6 ] exists as both a monomeric and a polymeric polymorph.…”

Section: Resultsmentioning

confidence: 99%

Fluorinated Weakly Coordinating Anions [M(hfip)₆]^– (M = Nb, Ta): Syntheses, Structural Characterizations and Computations

Preiss

Steinfeld

Scherer

et al. 2013

Zeitschrift anorg allge chemie

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The synthesis, spectroscopic and structural characterisation of a series of [M(hfip)6]– (M = Nb, Ta; hfip = O–C(H)(CF3)2) salts that are the typical starting materials to introduce these weakly coordinating anions by metathesis reactions into a given system is described. The salts Li[Nb(hfip)6] and Li[Ta(hfip)6] formed in 65 to 77 % yield from freshly sublimed MCl5 and Li[hfip]. By contrast, several attempts to synthesize Li[Sb(hfip)6] on the similar route (replace NbCl5 by SbCl5) failed to yield a pure product. Upon metathesis of the Li‐niobate with AgF in CH2Cl2, the pure Ag[Nb(hfip)6] formed. Mixing Li[Nb(hfip)6] with an equimolar amount of Cl–CPh3 in CH2Cl2 gave the yellow [CPh3][Nb(hfip)6]. Several of the compounds were characterized by X‐ray analysis. Thus, the crystal structures of the Li+‐ and Ag+‐solvates 1, 2‐C6H4F2{LiNb(hfip)6}2, [Li(H2O)][Ta(hfip)6], and [Ag(C6H5F)][Nb(hfip)6] as well as that of [CPh3][Nb(hfip)6] were solved and are described in this work.

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Indium: Organometallic Chemistry

Banger

2015

Encyclopedia of Inorganic and Bioinorganic Chemistry

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An update for select advances in the chemistry of organoindium compounds containing at least one In–C bond is reported. In particular, the various synthesis protocols to these are discussed, as well as characterization of homoleptic and heteroleptic organoindium derivatives; organoindium (0), (I), and ( II ) compounds; and anionic compounds is also reported. An examination of mixed metal complexes is also reported for both low valent systems as well as for In( III ) oxidation state. Furthermore, the use of organoindium compounds for thin film, nanotechnology organic synthesis, and catalysis is discussed.

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Synthesis and structural characterisation of gallium and indium fluoroalkoxide ‘ate’ complexes

Cited by 7 publications

References 51 publications

Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials

Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials

Fluorinated Weakly Coordinating Anions [M(hfip)₆]^– (M = Nb, Ta): Syntheses, Structural Characterizations and Computations

Indium: Organometallic Chemistry

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Synthesis and structural characterisation of gallium and indium fluoroalkoxide ‘ate’ complexes

Cited by 7 publications

References 51 publications

Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials

Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials

Fluorinated Weakly Coordinating Anions [M(hfip)6]– (M = Nb, Ta): Syntheses, Structural Characterizations and ­Computations

Indium: Organometallic Chemistry

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Fluorinated Weakly Coordinating Anions [M(hfip)₆]^– (M = Nb, Ta): Syntheses, Structural Characterizations and Computations