Synthesis and structural characterization of three supramolecular coordination polymers constructed from different metal ions and 2,2′-bipyridyl-3,3′-dicarboxylic acid

Under hydrothermal conditions, two new 3D actinide–silver (An–Ag) heterometallic coordination polymers, namely, [Ag(UO2)2(µ2‐OH)(bpdc)2(H2O)2]n (1) and [Ag3Th6(µ3‐O)(µ3‐OH)(µ2‐OH)6(bpdc)6(NO3)6·H2O]n (2, H2bpdc = 2,2′‐bipyridine‐3,3′‐dicarboxylic acid), were assembled through a hard–soft recognition strategy. Compounds 1 and 2 were characterized by single‐crystal X‐ray diffraction, powder X‐ray diffraction, and infrared spectroscopy. Both compounds are constructed through the bridging of infinite polynuclear An–bpdc chiral helical chains by AgI cations. Compound 2 represents the first ThIV–AgI heterometallic coordination polymer. Furthermore, the thermal stability and luminescence properties of 1 were studied.

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Two Three‐Dimensional Actinide–Silver Heterometallic Coordination Polymers Based on 2,2′‐Bipyridine‐3,3′‐dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs

Zhao

Mei

et al. 2017

Eur J Inorg Chem

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Two new coordination polymers employing 2,2′-bipyridine-3,3′,6,6′-tetracarboxylate as a ligand

Kochel

Hołyńska

2013

Inorganica Chimica Acta

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Synthesis, structure, fluorescence and thermochemical properties of the lanthanide complexes of 2-chloro-6-fluorobenzoic acid and 2,2′:6′2″-tripyridine ligands

Wang

Xu²,

Liu³

et al. 2022

Journal of Solid State Chemistry

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Synthesis and structural characterization of three supramolecular coordination polymers constructed from different metal ions and 2,2′-bipyridyl-3,3′-dicarboxylic acid

Cited by 9 publications

References 24 publications

Two Three‐Dimensional Actinide–Silver Heterometallic Coordination Polymers Based on 2,2′‐Bipyridine‐3,3′‐dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs

Two Three‐Dimensional Actinide–Silver Heterometallic Coordination Polymers Based on 2,2′‐Bipyridine‐3,3′‐dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs

Two new coordination polymers employing 2,2′-bipyridine-3,3′,6,6′-tetracarboxylate as a ligand

Synthesis, structure, fluorescence and thermochemical properties of the lanthanide complexes of 2-chloro-6-fluorobenzoic acid and 2,2′:6′2″-tripyridine ligands

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