Synthesis and structural characterization of three nano-structured Ag(I) coordination polymers; Syntheses, characterization and X-ray crystal structural analysis

Zisti, Fatemeh; Tehrani, Alireza Azhdari; Alizadeh, Robabeh; Abbasi, Hamed; Morsali, Ali; Eichhorn, S. Holger

doi:10.1016/j.jssc.2018.12.049

Cited by 10 publications

(3 citation statements)

References 52 publications

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“…Ag-CPs may undergo structural transformation induced by light, heating, , solvation, − desolvation, guest molecule, , and anion exchange ,,, stimuli. They can be used as precursors for the preparation of Ag nanoparticles by heating , or ultrasonic irradiation . Some of the investigated Ag-CPs form metallogels ,− showing interesting properties, such as the ability to sense hazardous gases .…”

Section: Introductionmentioning

confidence: 99%

“…They can be used as precursors for the preparation of Ag nanoparticles by heating 25,44 or ultrasonic irradiation. 45 tigated Ag-CPs form metallogels 28,46−52 showing interesting properties, such as the ability to sense hazardous gases. 49 Metallogels can also act as precursors for Ag-based nanoparticles which can be obtained in situ, 49 by a spontaneous reaction, 46 or upon exposure to light.…”

Section: Introductionmentioning

confidence: 99%

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1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study

Ristić

Todorović

Blagojević

et al. 2020

Crystal Growth & Design

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Four silver-based coordination polymers, {[Ag(L)2](BF4)}∞ (1), {[Ag(H2BTC)(L)]·(H3BTC)}∞ (2), {[Ag2(H2BTEC)(L)2]·3.33H2O}∞ (3), and [Ag(H25SSA)(L)]∞ (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H35SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036–0.056 min–1 range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet–singlet electronic excitations to the fluorescence, indicating that metal– intraligand transitions are responsible for luminescence in both complexes.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study

Ristić

Todorović

Blagojević

et al. 2020

Crystal Growth & Design

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“…Since the surface‐to‐volume ratio is high in these compounds, they have a lot more activities than their bulk . Therefore, a lot of studies have been carried out to synthesize these NCPs …”

Section: Introductionmentioning

confidence: 99%

Achieving Different Morphologies for a Zinc(II) Coordination Polymer by Green Sonochemical Synthesis and New Precursors for the Preparation of Zinc(II)oxide

et al. 2019

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A new 2D zinc(II) coordination polymer(CP) 1, [Zn(N 3 )(L)] n (1), [L = 2-picolinate] has been synthesized using branch tube approach. Nano and micro structures of CP 1 were synthesized using sonochemical technique in diverse conditions (different times and solvents) and they were identified by elemental analysis, FT-IR spectra, scanning electron microscopy (SEM) and powder X-ray diffraction (PXRD). Single-crystal X-ray studies show that CP1 contains Zn(II) atoms with different coordination geometries (tetrahedral and octahedral). The effects of solvents and reaction time on the morphology and size of the nano and microstructure of CP 1 were also evaluated. The results showed that change in reaction time has almost no effect on the size of particles, but change in solvent leads to changes in the morphology of particles.

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Advances on silver-based MOFs and/or CPs and their composites: Synthesis strategies and applications

Mondal,

Sahoo,

Behera

et al. 2024

Coordination Chemistry Reviews

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Synthesis and structural characterization of three nano-structured Ag(I) coordination polymers; Syntheses, characterization and X-ray crystal structural analysis

Cited by 10 publications

References 52 publications

1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study

1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study

Achieving Different Morphologies for a Zinc(II) Coordination Polymer by Green Sonochemical Synthesis and New Precursors for the Preparation of Zinc(II)oxide

Advances on silver-based MOFs and/or CPs and their composites: Synthesis strategies and applications

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