Synthesis and structural characterization of non-planar perfluoro phthalonitriles

Growth and characterization of thin films prepared from perfluoro-isopropyl-substituted perfluorophthalocyanines

“…In particular, F 16 Pc materials are interesting candidates for n-type channels in organic field effect transistors, being relatively stable even under ambient conditions [27,28]. A further step in the direction of orbital stabilization is represented by the introduction of perfluorinated alkyl groups as Pc ring substituents [29][30][31][32]. 1,4,8,11,15,18,22,25-octakisfluoro-2,3,9,10,16,17,23,24- [23,24].…”

Synthesis, photophysical and electrochemical properties of perfluoroisopropyl substituted binuclear phthalocyanine conjugated with a butadiyne linker

“…Zinc 23-iodo-1,4,8,11,15,18-hexafluoro-2,3,9,10,16,17-hexakis perfluoroisopropyl phthalocyaninate (7) was synthesized by tetramerization of perfluoro-(4,5-di-isopropyl)phthalonitrile [11], 4-iodophthalonitrile and zinc acetate dihydrate in a solvent-free condition at high temperature according to a standard procedure. This was then coupled with trimethylsilylacetylene under Sonogashira cross-coupling conditions to furnish trimethylsilylated ethynylphthalocyanine 8 in 79% yield.…”

Nitrogen and Hydrogen Adsorption by an Organic Microporous Crystal

“…A further 31 structures proved to have questionable values for density or a dubious structure as identified in the CSD or by using the CheckCIF online program and 27 structures could not be evaluated because of insufficient data (i.e., no available cif). The following structures satisfy the search criteria and are potential candidates for purely organic microporous crystals: ABINOP, [31] BALNIM, [24] EFALEC, [32] FAKTIV, [33] GIPTOO, [34] KETYEO, [35] NASQAA, [36] PETREM, [37] RERNEI, [38] SULDUY [39] TOZZIR, [40] WAVJAE, [41] XICRUW, [42] XOPYEG, [43] and YUPTIM. [44] In addition, the following metal-containing structures are candidates as microporous molecular crystals: ADIYIV, [45] FOSTEM, [46] FOSTEM10, [47] GOBSUL, [47] IKANOX, [48] KISYIV, [49] PICKAN, [50] and TIKFIC.…”