Synthesis and structure of bis(1,1-diethyl-3-(2-chlorobenzoyl)thioureido)nickel(II)

Bailey, R.A.; Rothaupt, K. L.; Kullnig, Rudolph K.

doi:10.1016/s0020-1693(00)83377-0

Cited by 53 publications

(13 citation statements)

References 5 publications

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“…Accordingly; the dihedral angle between these chelate planes is 3.4(1)°. The molecular structure is very close to the related 1,1-diethyl Ni complex [2] and shows similar short C-N and C-S bonds indicating the known p-bonding character in the chelate rings (d(C7-O1) = 1.269(4) Å, d(C8-S1) = 1.734(4) Å). The bond lengths and angles in the thiourea moiety are typical for compound.…”

Section: Discussionmentioning

confidence: 55%

Crystal structure of cis-bis(N,N-dimethyl-N′-4-chlorobenzoylthioureato) palladium(II), Pd(C10H10ClN2OS)2

Arslan

VanDerveer

Emen

et al. 2003

Zeitschrift Für Kristallographie - New Crystal Structures

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Section: Discussionmentioning

confidence: 55%

Crystal structure of cis-bis(N,N-dimethyl-N′-4-chlorobenzoylthioureato) palladium(II), Pd(C10H10ClN2OS)2

Arslan

VanDerveer

Emen

et al. 2003

Zeitschrift Für Kristallographie - New Crystal Structures

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“…[237][238][239] Three different coordination modes have been found so far for 1-(benzoyl)-3,3-(di-alkyl/aryl) thiourea ligands in their mononuclear transition metal complexes. They are a monobasic bidentate or chelating mode (O,S), [240] and neutral monodentate (S), [241] and neutral bidentate (O,N) [242] modes. An update of newly reported X-ray structures of metal complexes bearing 1-(acyl)-substituted thioureas is presented in Table S3 in the Supporting Information.…”

Section: Metal Complexesmentioning

confidence: 99%

A review on the chemistry, coordination, structure and biological properties of 1-(acyl/aroyl)-3-(substituted) thioureas

Saeed

Flörke

Erben

2013

Journal of Sulfur Chemistry

198

123

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This review provides an overview of the chemistry, structure and potential applications of 1-(acyl/aroyl)-3-(mono-substituted) and 1-(acyl/aroyl)-3,3-(di-substituted) thioureas, with general formula R 1 C(O)N (1) HC(S)N (3) R 2 R 3 . In recent years, the title compounds have found extensive applications as ligands in coordination chemistry. The effect that nitrogen substituents exert on the intra-and intermolecular hydrogen-bonding interactions is discussed, including their role on the coordination properties displayed by these ligands. Novel applications of transition metal complexes bearing 1-(acyl/aroyl)-3-(mono-and di-substituted) thioureas are introduced. Biological aspects are also highlighted. As recently demonstrated, high-throughput screening assay and structure-activity analyses are feasible for this class of compounds. The chemical versatility of 1-(acyl)-3-(substituted) thiourea molecules and the derived metal complexes, together with the possibility of determining detailed structural properties, join biological applications in a promising interdisciplinary approach. The bibliography includes 382 references with emphasis on the literature appearing after 2007.

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“…The interplay of intermolecular and intramolecular hydrogen bonding has direct relevance on chemical properties of these compounds, including their use as ligand in metal complexes [26] and also their conformational properties, which have influence in the applied fields [27]. Metal complexes of these compounds have long been known not only for their wide range of biological applications but also for their role in analytical sciences [28][29][30], as inhibitors in the corrosion field [31] and as catalysts in chemical reactions [21,32].…”

Section: Introductionmentioning

confidence: 99%

Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands

et al. 2018

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Thiourea derivatives [N-(di-n-propylcarbamothioyl)-4-fluorobenzamide (HL1) and N-(di-n-propylcarbamothioyl)-4-bromobenzamide (HL2)] and their platinum complexes have been successfully synthesized and structurally characterized by spectroscopic 1H NMR, 13C NMR, COSY, HMQC, and FT-IR techniques. The structure of both complexes was also confirmed by single crystal X-ray diffraction studies. The study of X-ray single crystal diffraction shows that the supramolecular aggregation of the complexes is stabilized via weak interactions as well as stacking interactions such as C-H···π and π···π. The cis-[Pt(L1-S,O)2 showed C–H···π and π···π stacking interactions, whereas only C–H···π stacking interaction was observed in cis-[Pt(L2-S,O)2]. In addition, the strong classical and non-classical intermolecular hydrogen bonds are not found in the prepared complexes. Therefore, it can be said that the C–H···π and π···π stacking interactions play an important role in the formation of supramolecular structures of the complexes.

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Synthesis and structure of bis(1,1-diethyl-3-(2-chlorobenzoyl)thioureido)nickel(II)

Cited by 53 publications

References 5 publications

Crystal structure of cis-bis(N,N-dimethyl-N′-4-chlorobenzoylthioureato) palladium(II), Pd(C10H10ClN2OS)2

Crystal structure of cis-bis(N,N-dimethyl-N′-4-chlorobenzoylthioureato) palladium(II), Pd(C10H10ClN2OS)2

A review on the chemistry, coordination, structure and biological properties of 1-(acyl/aroyl)-3-(substituted) thioureas

Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands

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