2014
DOI: 10.1016/j.jfluchem.2013.10.014
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Synthesis and structure of [CeF4(Me2SO)2]—A rare neutral ligand complex of a lanthanide tetrafluoride

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Cited by 11 publications
(3 citation statements)
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“…They too are likely to contain only lattice/surface water. 32 The wider implications of these results in metal fluoride coordination chemistry suggest that for other metals, only those 'hydrated' fluorides that contain water within the metal coordination sphere, are likely to be viable synthons for neutral ligand complexes.…”
Section: Attempted Synthesis From Mfmentioning
confidence: 99%
“…They too are likely to contain only lattice/surface water. 32 The wider implications of these results in metal fluoride coordination chemistry suggest that for other metals, only those 'hydrated' fluorides that contain water within the metal coordination sphere, are likely to be viable synthons for neutral ligand complexes.…”
Section: Attempted Synthesis From Mfmentioning
confidence: 99%
“…Probably as a result of the high lattice energies of lanthanide fluorides, there are no reports of phosphine oxide complexes with LnF 3 and attempts to prepare CeF 4 complexes using [CeF 4 (DMSO) 2 ] as a precursor were unsuccessful [43]. [47].…”
Section: Complexes With Lanthanide Halidesmentioning
confidence: 99%
“…9, have been determined and show the europium to be square antiprismatic in [Eu(CF 3 COCDCOCF 3 ) 3 (19) The photophysical properties of the complexes showed that [Eu (CF 3 COCDCOCF 3 ) 3 (41) 2 ] has a very sharp red emission with a wide stimulated emission cross-section. Complexes of (26), (43) and 44 antiprismatic about the europium ion [109,110]. The complex of (44) in particular, has a high emission quantum yield of 83%.…”
Section: Complexes With Lanthanide B-diketonatesmentioning
confidence: 99%