1987
DOI: 10.1038/330360a0
|View full text |Cite|
|
Sign up to set email alerts
|

Synthesis and structure of (cis)-[1-ferrocenyl-2-(4-nitrophenyl)ethylene], an organotransition metal compound with a large second-order optical nonlinearity

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1

Citation Types

2
171
0

Year Published

1998
1998
2017
2017

Publication Types

Select...
8

Relationship

0
8

Authors

Journals

citations
Cited by 420 publications
(173 citation statements)
references
References 0 publications
2
171
0
Order By: Relevance
“…These observations are compatible with those of complex A. Green and co-workers reported that A showed three absorptions in heptane, whereas in DMF it showed only two absorptions [5]. Marder and co-workers reported that the UV-vis absorption spectra of acceptor substituted ferrocenylethylenes typically have two strong bands that are attributed to charge-transfer transitions [8].…”
supporting
confidence: 76%
See 2 more Smart Citations
“…These observations are compatible with those of complex A. Green and co-workers reported that A showed three absorptions in heptane, whereas in DMF it showed only two absorptions [5]. Marder and co-workers reported that the UV-vis absorption spectra of acceptor substituted ferrocenylethylenes typically have two strong bands that are attributed to charge-transfer transitions [8].…”
supporting
confidence: 76%
“…They reported that analysis of the cyclic voltammograms exhibited this substituent makes the electron removal easier with respect to ferrocene by about 100 mV. As the electron-accepting group we chose nitrobenzene conjugating moiety, which enhances the molecular hyperpolarisabilities of the compound [5]. The synthetic route commenced with known ferrocenyl dicarbaldehyde 2.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…15 Although the preparation of some non-linear molecules containing ferrocene as the donor group, such as 1, 2, 3 and 4 ( Fig. 1), have been accomplished, [16][17][18][19][20] , these reported ferrocenyl derivatives contain long conjugated systems and result in low solubility in common organic solvents.…”
Section: Introductionmentioning
confidence: 98%
“…A molecule containing a pushing moiety and a pulling moiety in a conjugating system may have large second-order optical nonlinearities. 4 Green et al 5 first reported a large secondorder optical nonlinearity of organometallic compounds containing a ferrocenyl group. Actually, the ferrocenyl group is an excellent π -donor in conjugating chains.…”
Section: Introductionmentioning
confidence: 99%