1984
DOI: 10.1016/s0040-4039(01)80260-4
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Synthesis and structure of triply bridged purinophanes

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Cited by 12 publications
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“…The smaller the bridging chain, the greater the deformation of the purine p system. Sakata and coworkers [76][77][78] have investigated several purinophanes as models for stacking interactions of nucleic acid bases. The bathochromic shift of the n-p* transition is also a reflection of the molecular geometry, in particular with respect to the conformation of the amino group and its interaction with the aromatic p system.…”
Section: Heterocyclophanesmentioning
confidence: 99%
“…The smaller the bridging chain, the greater the deformation of the purine p system. Sakata and coworkers [76][77][78] have investigated several purinophanes as models for stacking interactions of nucleic acid bases. The bathochromic shift of the n-p* transition is also a reflection of the molecular geometry, in particular with respect to the conformation of the amino group and its interaction with the aromatic p system.…”
Section: Heterocyclophanesmentioning
confidence: 99%