Synthesis and structures of the silyl bridged bis(indenyl) diruthenium complexes and a novel indenyl nonanuclear ruthenium cluster Ru9(μ6-C)(CO)14(μ3-η5:η2:η2-C9H7)2

Chen, Dafa; Mu, Bin; Xu, Shansheng; Wang, Baiquan

doi:10.1016/j.jorganchem.2006.05.030

Cited by 13 publications

(3 citation statements)

References 128 publications

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“…Structural data reported for silyl−transition metal complexes prepared from hydrosilanes that include both “classical” M−Si, M−H, and/or Si−H bonds and “nonclassical” M···H···Si interactions as well as silylene complexes (formed from hydrosilanes) are summarized in Table and includes entries from Tables , , and as well as additional complexes listed in the footnotes to these tables. Data for Si−TM bond distances reported for silyl−metal complexes prepared by routes that did not involve hydrosilanes and that have been reported in the Cambridge Data Base through Mar 2009 (version 5.30) are recorded in the footnotes to Table . …”

Section: Solid-state Structuresmentioning

confidence: 99%

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

2011

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Section: Solid-state Structuresmentioning

confidence: 99%

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

2011

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“…Ind is an aromatic ten π- electron system. Only a few examples of bridged bis(Ind) dinuclear metal complexes have been reported, – mainly because of the poor reactivity of the Ind ligands …”

Section: Systems With Aromatic Rings As Bridgesmentioning

confidence: 99%

“…Wang et al have studied the synthesis and structures of silyl bridged bis(Ind) diruthenium complexes. The general reaction path to incorporate Ru 3 (CO) 12 into an indene bridge is to heat the indene ligand and Ru 3 (CO) 12 in a refluxing high boiling point alkane, such as heptane.…”

Section: Systems With Aromatic Rings As Bridgesmentioning

confidence: 99%

Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes

2010

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Contents 1. Introduction and Scope of Review 4839 2. Theoretical Aspects 4840 2.1. Mixed-Valence Systems 4840 2.2. Electron-Transfer Theory 4840 2.3. Electrochemistry 4842 2.4. EPR and 57 Fe-Mo ¨ssbauer Spectroscopy 4843 2.5. NMR Spectroscopy and X-ray Crystallography 4843 2.6. Theoretical Calculations 4844 2.7. IR Spectroscopy 4844 2.8. Classification and General Properties 4844 3. Systems with Unsaturated Carbon Chain Bridges 4844 3.1. All-Carbon sp-Bridged Systems 4845 3.2. Carbon-Based sp 2 -Bridged Systems 4848 3.3. Carbon-Based sp/sp 2 -Bridged Systems 4851 4. Systems with Aromatic Rings as Bridges 4856 4.1. Fulvalene and Fulvalene-like Bridged Systems 4856 4.

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Reactions of Pyridyl Side Chain Functionalized Indenes with Ru₃(CO)₁₂

Chen

Song

et al. 2008

Eur J Inorg Chem

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Reactions of the pyridyl side chain functionalized indenes 3‐R‐C9H7 [R = (C5H4N)CH2CMe2 (1), (MeC5H3N)CH2CMe2 (2), (C5H4N)CH2 (6)] with Ru3(CO)12 in refluxing xylene gave the facial coordinated indenyl cluster [μ3‐η5:η2:η2‐(C5H3N)CH2Me2C(C9H6)]Ru4(μ3‐CO)(CO)7 (8), the syn‐η5:η6‐coordinated indenyl cluster [μ‐η5:η6‐(MeC5H3N)CH2CMe2(C9H6)Ru2(CO)3]2 (10), and the η1:η2‐coordinated indenyl complex[η2‐(C5H3N)CH2(C9H7)][η1:η2‐(C5H4N)CH2(C9H6)]Ru2(CO)4(18), respectively, in addition to the normal diruthenium complexes [(η5‐RC9H6)Ru(CO)]2(μ‐CO)2 [R = (C5H4N)CH2CMe2 (7), (MeC5H3N)CH2CMe2 (9), (C5H4N)CH2 (17)]. When the pyridyl side chains were replaced by other bulky groups [R = tBu (3), PhCH2Me2C (4), (C9H6N)CH2Me2C (5)], the similar syn‐η5:η6‐coordinated indenyl clusters 12, 14, and 16 were also obtained. When 1 or 2 were treated with Ru3(CO)12 in refluxing heptane, the ionic clusters {[(C5H4N)CH2Me2C(C9H6)]Ru(CO)2}+[HRu6(CO)18]– (19), [(C5H4N)CH2Me2C(C9H8)]+[HRu6(CO)18]– (20), and complex 8 or ionic clusters {[(MeC5H3N)CH2Me2C(C9H6)]Ru(CO)2}+[HRu6(CO)18]– (21) and [(MeC5H3N)CH2Me2C(C9H8)]+[HRu6(CO)18]– (22) were obtained. Similar treatment of 5 or 6 with Ru3(CO)12 in refluxing heptane gave the ionic clusters [(C9H6N)CH2Me2C(C9H8)]+[HRu6(CO)18]– (23) or {[η3‐(C5H4N)CH(C9H7)][η2‐(C5H4N)CH2(C9H7)]Ru(CO)}+[HRu6(CO)18]– (24), respectively, in addition to complex 18 in the latter case. The molecular structures of 8, 9, 10, 14, 17, 18, 21, 22, and 24 were determined by X‐ray diffraction analysis.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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Synthesis and structures of the silyl bridged bis(indenyl) diruthenium complexes and a novel indenyl nonanuclear ruthenium cluster Ru9(μ6-C)(CO)14(μ3-η5:η2:η2-C9H7)2

Cited by 13 publications

References 128 publications

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes

Reactions of Pyridyl Side Chain Functionalized Indenes with Ru₃(CO)₁₂

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Synthesis and structures of the silyl bridged bis(indenyl) diruthenium complexes and a novel indenyl nonanuclear ruthenium cluster Ru9(μ6-C)(CO)14(μ3-η5:η2:η2-C9H7)2

Cited by 13 publications

References 128 publications

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes

Reactions of Pyridyl Side Chain Functionalized Indenes with Ru3(CO)12

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Reactions of Pyridyl Side Chain Functionalized Indenes with Ru₃(CO)₁₂