2020
DOI: 10.26434/chemrxiv.11336852
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Synthesis and styrene copolymerization of halogen novel ring-substituted isobutyl phenylcyanoacrylates

Abstract: <p>Novel dihalogen ring-substituted isopropyl 3-phenyl-2-cyanoacrylates, RPhCH=C(CN)CO<sub>2</sub>CH(CH<sub>3</sub>)<sub>2</sub> (where R is 2,5-dibromo, 3,5-dibromo, 2,3-dichloro, 2,4-dichloro, 2,5-dichloro, 2,6-dichloro, 3,4-dichloro, 3,5-dichloro, 2,4-difluoro, 2,5-difluoro, 2,6-difluoro) were prepared and copolymerized with styrene. The acrylates were synthesized by the piperidine catalyzed Knoevenagel condensation of ring-disubstituted benzaldehydes and isopropyl … Show more

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