Synthesis and Transport Properties of Nanostructured VO2 by Mechanochemical Processing

Billik, Peter; Čaplovičová, Mária; Manka, Jason; Čaplovič, Ľubomír; Cigáň, A.; Koňakovský, A.; Bystrický, Roman; Dvurečenskij, A.

doi:10.2478/v10048-011-0001-6

Cited by 7 publications

(1 citation statement)

References 29 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[36][37][38] Vanadium oxide nanoparticles have been synthesised using a variety of methods, including: pyrolysis, 39 sol-gel, 40 hydrothermal methods 41 and ball milling 42 for use in coatings.…”

Section: -35mentioning

confidence: 99%

[{VOCl₂(CH₂(COOEt)₂)}₄] as a molecular precursor for thermochromic monoclinic VO₂ thin films and nanoparticles

et al. 2016

View full text Add to dashboard Cite

The synthesis of thermochromic monoclinic vanadium(IV) oxide (VO 2 (M)) thin films and vanadium oxide nanocrystals from a molecular precursor, [{VOCl 2 (CH 2 (COOEt) 2 )} 4 ] is described. Thin films were synthesised using aerosol assisted chemical vapour deposition (AACVD) onto glass substrates at high temperatures and were subsequently characterised and tested for thermochromic efficiency. The film's suitability as smart, energy efficient window coatings was investigated by calculating their solar modulation potential. Thin films were also doped with tungsten to lower their metal to semiconductor transition temperature (MST) through the addition of tungsten(VI) phenoxide during the AACVD process, lowering the MST from a typical B70 1C for an undoped VO 2 (M) thin film to B50 1C for a typical W-doped example. The optimum deposition temperature of 550 1C produced films with thermochromic properties (solar modulation of 15.9%) comparable to the highest values reported. In addition, vanadium oxide nanostructures were synthesised using the thermal decomposition of [{VOCl 2 (CH 2 (COOEt) 2 )} 4 ] and their shape controllably tailored by varying surfactant concentration and type. Thin films and nanostructures were characterised using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and energy-dispersive X-ray spectroscopy (EDS). Thermochromic measurements were measured using UV-Vis spectroscopy with a variable temperature stage.

show abstract

Section: -35mentioning

confidence: 99%

[{VOCl₂(CH₂(COOEt)₂)}₄] as a molecular precursor for thermochromic monoclinic VO₂ thin films and nanoparticles

et al. 2016

View full text Add to dashboard Cite

show abstract

One-step ball milling synthesis of VO2 (M) nanoparticles with exemplary thermochromic performance

Wang

Liu

et al. 2021

SN Appl. Sci.

View full text Add to dashboard Cite

Vanadium dioxide (VO2) has demonstrated highly potential for smart windows because of its thermochromic property. This study represents the development of a facile but efficient method for the synthesis of VO2 (M) nanoparticles by ball milling method under ambient conditions, without release of waste liquid or gases. The key variables related to synthesis, including milling time and molar ratio of raw materials, have been investigated. It was found that the pure-phase VO2 (M) nanoparticles with the sizes of the particles ranged from 20 to 50 nm and relatively good dispersivity could be prepared by optimizing process parameters. For practice use to decrease the phase transition temperature, elemental W doping amount of 2 at.%, V1−xWxO2 (M) nanoparticles were also studied, and their glass coating exhibits high thermochromic performance with luminous transmittance (Tlum) of 44.18%, solar regulation efficiency (∆Tsol) of 9.64%, and the critical phase transition temperature (Tc) of ~ 42 °C. This work demonstrates a green and promising ball milling method to fabricate large scale VO2 (M) and V1−xWxO2 (M) nanoparticles for smart windows.

show abstract

Fabrication of pure monoclinic VO2 nanoporous nanorods via a mild pyrolysis process

Jung

Kim

Cho

2018

Ceramics International

View full text Add to dashboard Cite

Synthesis and Transport Properties of Nanostructured VO2 by Mechanochemical Processing

Cited by 7 publications

References 29 publications

[{VOCl₂(CH₂(COOEt)₂)}₄] as a molecular precursor for thermochromic monoclinic VO₂ thin films and nanoparticles

[{VOCl₂(CH₂(COOEt)₂)}₄] as a molecular precursor for thermochromic monoclinic VO₂ thin films and nanoparticles

One-step ball milling synthesis of VO2 (M) nanoparticles with exemplary thermochromic performance

Fabrication of pure monoclinic VO2 nanoporous nanorods via a mild pyrolysis process

Contact Info

Product

Resources

About

Synthesis and Transport Properties of Nanostructured VO2 by Mechanochemical Processing

Cited by 7 publications

References 29 publications

[{VOCl2(CH2(COOEt)2)}4] as a molecular precursor for thermochromic monoclinic VO2 thin films and nanoparticles

[{VOCl2(CH2(COOEt)2)}4] as a molecular precursor for thermochromic monoclinic VO2 thin films and nanoparticles

One-step ball milling synthesis of VO2 (M) nanoparticles with exemplary thermochromic performance

Fabrication of pure monoclinic VO2 nanoporous nanorods via a mild pyrolysis process

Contact Info

Product

Resources

About

[{VOCl₂(CH₂(COOEt)₂)}₄] as a molecular precursor for thermochromic monoclinic VO₂ thin films and nanoparticles

[{VOCl₂(CH₂(COOEt)₂)}₄] as a molecular precursor for thermochromic monoclinic VO₂ thin films and nanoparticles