Synthesis and tuberculostatic activity of S-acylvinyl-N, N-dialkyldithiocarbamates and 2-(diethylimmonium)-4-acylmethyl-4-phenyl-1, 3-dithietane perchlorates

Елохина, В. Н.; Нахманович, А. С.; Aleksandrova, A. E.; Bishnevskii, B. I.; Kalikhman, I. D.

doi:10.1007/bf01148637

Cited by 4 publications

(3 citation statements)

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“…The antibacterial effect of dithiocarbamates was reported to arise by the reaction of HS-groups with physiologically important enzymes by transferring the alkyl group of the dithioester to the HS-function of the enzyme [7]. Investigations of various types of compounds possessing aminoalkylation ability showed that substituted aminoethyl N,N-dialkyldithiocarbamates have cytostatic features presumably via a similar mechanism proposed for antibacterial action [8].…”

Section: Introductionmentioning

confidence: 97%

Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro

Khan

Nami

Siddiqi

2008

Journal of Organometallic Chemistry

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Section: Introductionmentioning

confidence: 97%

Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro

Khan

Nami

Siddiqi

2008

Journal of Organometallic Chemistry

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“…[32][33][34][35][36][37][38][39][40][41][42] Indeed, it is reported that CS 2 is capable of efficiently reacting with secondary amines to form more nucleophilic dithiocarbamic acid derivatives, 43,44 which could react with activated internal alkynes in a spontaneous manner. 45 Thus, CS 2 acts as a "wedge" in this reaction. As a result, S-acylvinyl-N,N-dialkyl dithiocarbamates (ADDCs) could be produced more facilely than previously reported reactions.…”

Section: Introductionmentioning

confidence: 99%

Green synthesis of sulfur-containing polymers by carbon disulfide-based spontaneous multicomponent polymerization

Chen,

Qin,

Tang

2024

Green Chem.

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“…[30][31][32][33][34][35][36][37][38][39][40] Indeed, it is reported that CS2 is capable to efficiently react with secondary amines to form more nucleophilic dithiocarbamic acid derivatives, 41,42 which could react with activated internal alkynes in a spontaneous manner. 43 Thus, CS2 acts as a "wedge" in this MCP. As a result, S-acylvinyl-N,N-dialkyl dithiocarbamates (ADDC) could be produced more facilely than previously reported reactions.…”

Section: Introductionmentioning

confidence: 99%

Green Synthesis of Sulfur-Containing Polymers by Carbon Disulfide-based Spontaneous Multicomponent Polymerization

Chen,

Qin,

Tang

2023

Preprint

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Sulfur-containing polymers have gained much attention in polymer science due to their unique properties. Nevertheless, their preparation has posed considerable challenges, particularly in diversifying their structures and achieving highly efficient polymerizations. This is especially true for the polymers derived from CS2, a readily available one-carbon (C1) feedstock, as their synthesis often necessitates harsh conditions or results in unexpected byproducts. In this work, we established a regio-selective and atom-economy spontaneous multicomponent polymerization based on carbonyl or ester group-activated internal alkynes, commercially available amines, and CS2. Similar to the angled half lap joint of two plates in a scarf joint of in ancient Chinese tenon and mortise architecture, these internal ethynyl and amino groups can not readily react at room temperature. However, the addition of CS2 acts as a "wedge," making the polymerization spontaneous and enabling the tight linkage and extension of these functional groups into stable polymer chains. The sulfur-containing polymers with satisfactory weight-average molecular weights (up to 31 600) were produced in high yields (up to 97%). The resultant polymers exhibit exceptional characteristics, including high refractive indices (up to 1.7471 at 632.8 nm), excellent light transmittance, and good film-forming capabilities. This work opens up a new avenue for the green and efficient synthesis of functional sulfur-containing polymers, using cost-effective CS2 as starting material.

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Synthesis and tuberculostatic activity of S-acylvinyl-N, N-dialkyldithiocarbamates and 2-(diethylimmonium)-4-acylmethyl-4-phenyl-1, 3-dithietane perchlorates

Cited by 4 publications

References 1 publication

Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro

Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro

Green synthesis of sulfur-containing polymers by carbon disulfide-based spontaneous multicomponent polymerization

Green Synthesis of Sulfur-Containing Polymers by Carbon Disulfide-based Spontaneous Multicomponent Polymerization

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