Synthesis and Vibrational and Mass Spectra of (n-Bu)2Sn(O2PMe2)2, (n-Bu)2Sn(O2PMePh)2 and (n-Bu)2Sn(O2PPh2)2

Shihada, Abdel-Fattah

doi:10.1515/znb-1995-0510

Zeitschrift Für Naturforschung B

1995

DOI: 10.1515/znb-1995-0510

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Synthesis and Vibrational and Mass Spectra of (n-Bu)₂Sn(O₂PMe₂)₂, (n-Bu)₂Sn(O₂PMePh)₂ and (n-Bu)₂Sn(O₂PPh₂)₂

Abdel-Fattah Shihada¹

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Crystal Structures of [Bu₂Sn(O₂PPh₂)₂], [Ph₂Sn(O₂PPh₂)₂], and [PhClSn(O₂PPh₂)OMe]₂. Raman Spectra of [Ph₂Sn(O₂PPh₂)₂] and [PhClSn(O₂PPh₂)OMe]₂

Shihada

Weller

2006

Zeitschrift anorg allge chemie

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n-Bu) 2 Sn(O 2 PPh 2 ) 2 ] (1), and [Ph 2 Sn(O 2 PPh 2 ) 2 ] (2) have been synthesized by the reactions of R 2 SnCl 2 (Rϭn-Bu, Ph) with HO 2 PPh 2 in Methanol. From the reaction of Ph 2 SnCl 2 with diphenylphosphinic acid a third product [PhClSn(O 2 PPh 2 )OMe] 2 (3) could be isolated. X-ray diffraction studies show 1 to crystallize in the monoclinic space group P2 1 /c with a ϭ 1303.7(1) pm, b ϭ 2286.9(2) pm, c ϭ 1063.1(1) pm, β ϭ 94.383(6)°, and Z ϭ 4. 2 crystallizes triclinic in the space group P1, the cell parameters being a ϭ 1293.2(2) pm, b ϭ 1478.5(4) pm, c ϭ 1507.2(3) pm, α ϭ 98.86(3)°, β ϭ 109.63(2)°, γ ϭ 114.88(2)°, and Z ϭ 2. Both com-

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Crystal Structures of [Bu₂Sn(O₂PPh₂)₂], [Ph₂Sn(O₂PPh₂)₂], and [PhClSn(O₂PPh₂)OMe]₂. Raman Spectra of [Ph₂Sn(O₂PPh₂)₂] and [PhClSn(O₂PPh₂)OMe]₂

Shihada

Weller

2006

Zeitschrift anorg allge chemie

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Crystal Structures and Spectral Studies of [Ph₃Sn(O₂AsMe₂)], [Bu₂ClSn(O₂AsMe₂)] and [PhClSn(O₂AsMe₂)(μ‐OMe)]₂

Shihada

Weller

2007

Zeitschrift anorg allge chemie

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[Ph3Sn(O2AsMe2)] (1) and [PhClSn(O2AsMe2)(μ‐OMe)]2 (3) have been synthesized by treatment of Ph3SnCl and Ph2SnCl2 with Na(O2AsMe2) in methanol, respectively. [Bu2ClSn(O2AsMe2)] (2) has been prepared by the reaction of Bu2SnCl2 with HO2AsMe2 in methanol. X‐ray diffraction studies show 1 to crystallize in the monoclinic space group P21/n with a = 699.8(1), b = 1961.4(2), c = 1433.6(2) pm, β = 95.17(1)°, and Z = 4. 2 also crystallizes monoclinic in the space group P21/m, the cell parameters being a = 480.6(1), b = 1992.7(2), c = 808.8(1) pm, β = 103.726(5)°, and Z = 2. Both compounds form infinite chains with alternating (Me2AsO2)− and (R3Sn)+ or (R2ClSn)+ units. The dimer 3 consists of 8‐membered (OSnOAs)2 rings in which the tin atoms are bridged by methanolate bridges. It crystallizes triclinic in the space group $\rm P{\bar 1}$ with a = 822.8(2), b = 910.4(2), c = 929.2(2) pm, α = 77.04(3)°, β = 82.35(3)°, γ = 68.69(3)°, and Z = 1 for the dimer. The vibrational and mass spectra of 1, 2 and 3 are given and discussed.

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Synthesis and Vibrational and Mass Spectra of (n-Bu)₂Sn(O₂PMe₂)₂, (n-Bu)₂Sn(O₂PMePh)₂ and (n-Bu)₂Sn(O₂PPh₂)₂

Cited by 2 publications

References 4 publications

Crystal Structures of [Bu₂Sn(O₂PPh₂)₂], [Ph₂Sn(O₂PPh₂)₂], and [PhClSn(O₂PPh₂)OMe]₂. Raman Spectra of [Ph₂Sn(O₂PPh₂)₂] and [PhClSn(O₂PPh₂)OMe]₂

Crystal Structures of [Bu₂Sn(O₂PPh₂)₂], [Ph₂Sn(O₂PPh₂)₂], and [PhClSn(O₂PPh₂)OMe]₂. Raman Spectra of [Ph₂Sn(O₂PPh₂)₂] and [PhClSn(O₂PPh₂)OMe]₂

Crystal Structures and Spectral Studies of [Ph₃Sn(O₂AsMe₂)], [Bu₂ClSn(O₂AsMe₂)] and [PhClSn(O₂AsMe₂)(μ‐OMe)]₂

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Synthesis and Vibrational and Mass Spectra of (n-Bu)2Sn(O2PMe2)2, (n-Bu)2Sn(O2PMePh)2 and (n-Bu)2Sn(O2PPh2)2

Cited by 2 publications

References 4 publications

Crystal Structures of [Bu2Sn(O2PPh2)2], [Ph2Sn(O2PPh2)2], and [PhClSn(O2PPh2)OMe]2. Raman Spectra of [Ph2Sn(O2PPh2)2] and [PhClSn(O2PPh2)OMe]2

Crystal Structures of [Bu2Sn(O2PPh2)2], [Ph2Sn(O2PPh2)2], and [PhClSn(O2PPh2)OMe]2. Raman Spectra of [Ph2Sn(O2PPh2)2] and [PhClSn(O2PPh2)OMe]2

Crystal Structures and Spectral Studies of [Ph3Sn(O2AsMe2)], [Bu2ClSn(O2AsMe2)] and [PhClSn(O2AsMe2)(μ‐OMe)]2

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Synthesis and Vibrational and Mass Spectra of (n-Bu)₂Sn(O₂PMe₂)₂, (n-Bu)₂Sn(O₂PMePh)₂ and (n-Bu)₂Sn(O₂PPh₂)₂

Crystal Structures of [Bu₂Sn(O₂PPh₂)₂], [Ph₂Sn(O₂PPh₂)₂], and [PhClSn(O₂PPh₂)OMe]₂. Raman Spectra of [Ph₂Sn(O₂PPh₂)₂] and [PhClSn(O₂PPh₂)OMe]₂

Crystal Structures of [Bu₂Sn(O₂PPh₂)₂], [Ph₂Sn(O₂PPh₂)₂], and [PhClSn(O₂PPh₂)OMe]₂. Raman Spectra of [Ph₂Sn(O₂PPh₂)₂] and [PhClSn(O₂PPh₂)OMe]₂

Crystal Structures and Spectral Studies of [Ph₃Sn(O₂AsMe₂)], [Bu₂ClSn(O₂AsMe₂)] and [PhClSn(O₂AsMe₂)(μ‐OMe)]₂