2017
DOI: 10.22147/juc/130103
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Synthesis, Characteristic, Catalytic and Antimicrobial activities of Imidazolo substituted Benzylidene imines with Ruthenium (III) complexes

Abstract: The synthesis and characterization of several Hexa -coordinated Ru(III) complexes of the type [RuCl(CO) (EPh 3 ) 2 (L)] (E = P or As ; L = monobasic bidentate anion) were reported. FTIR, Electronic, EPR, electrochemistry and catalytic activity of the complexes were discussed. An octahedral geometry has been tentatively proposed for all these complexes. The new complexes have been subjected to antimicrobial investigations are also discussed.

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“…The IR spectra of the complexes (1-5) contain many sharp bands of different intensities due to the vibrations arising from the coligands (L1-L5) and 2, 2'-bipyridine. The νC=N stretching frequency of the free ligands (L1-L5) appears near 1607 cm -1 has been shifted to 1602 cm -1 in the present complexes in accordance with the coordination of the azomethine function to the metal ion 23,24 . In the IR spectra of all the ligands, a sharp band observed in the region of 1506-1544 cm -1 has been assigned to νC=C stretching frequency.…”
Section: Fig 2 Electronic Absorbance Spectra Of Ruthenium Complexes supporting
confidence: 70%
“…The IR spectra of the complexes (1-5) contain many sharp bands of different intensities due to the vibrations arising from the coligands (L1-L5) and 2, 2'-bipyridine. The νC=N stretching frequency of the free ligands (L1-L5) appears near 1607 cm -1 has been shifted to 1602 cm -1 in the present complexes in accordance with the coordination of the azomethine function to the metal ion 23,24 . In the IR spectra of all the ligands, a sharp band observed in the region of 1506-1544 cm -1 has been assigned to νC=C stretching frequency.…”
Section: Fig 2 Electronic Absorbance Spectra Of Ruthenium Complexes supporting
confidence: 70%