Synthesis, characterization, and application of novel trihexyl tetradecyl phosphonium bis (2,4,4-trimethylpentyl) phosphinate for extractive desulfurization of liquid fuel

Phosphonium salts and P-ylides

“…197 Dharaskar et al focussed on the use of [P 66614 ] [bis(2,2,4-trimethylpentyl) phosphinate], for the extraction of benzothiophene from n-dodecane as fuel model. 198 Coutinho's group has been very active in the field of extraction of organic compounds by ILs. Of note were the study of (i) aqueous micellar two-phase systems with PILs as co-surfactants for the selective extraction of (bio)molecules.…”

Dearomatization of pyrolysis gasolines from mild and severe cracking by liquid–liquid extraction using a binary mixture of [4empy][Tf2N] and [emim][DCA] ionic liquids

“…ILs have been extensively studied in the dearomatization, denitrogenation, and desulfuration of liquid fuels, showing good extractive properties and a nonvolatile nature that could reduce investment and operating costs of the extraction units [4][5][6][7][8][9][10][11][12][13][14][15][16]. A wide number of pure ILs have been specifically applied in the liquid-liquid extraction of benzene, toluene, or xylenes from binary mixtures with an aliphatic hydrocarbon [4,11].…”

FeCl3 Based Imidazolium Ionic Liquids as Novel Solvents for Extractive–Oxidative Desulfurization of Liquid Fuels

“…Many organic solvents such as ethers, amines, alcohols and other volatile organic compounds have been used for options like extraction, absorption, azeotropic distillation, etc., [9,10]. Conventional solvents have their own limitations in terms of environmental issues, recyclability, etc., which can be overcome by the use of ILs as green solvents [11,12].…”