Synthesis, characterization and applications of polymer-metal chelates derived from poly[((4-acryloxy acetophenone)-divinylbenzene)] benzoyl hydrazone resins

Abstract

4-Acryloxy acetophenone was prepared and subjected to suspension polymerization with divinylbenzene as a cross-linking agent. The resulting network polymer was ligated with benzoyl hydrazone. The functional polymer was treated with metal ions [Cu(II), Fe(II)]. The polymer-metal complexes obtained were characterized by elemental analysis, IR, 1H-NMR, solid state 13 C cross-polarization magic-angle spinning (CP/MAS) NMR, electron paramagnetic resonance (EPR), thermogravimetric and scanning electron microscopy (SEM) studies. The maximum uptake efficiency for the metal ions was determined. The reusability of the polymer ligand was tested and it was shown that even after four cycles, the efficiency of the uptake was not altered.

Rigid and Strong Thermoresponsive Shape Memory Hydrogels Transformed from Poly(vinylpyrrolidone-co-acryloxy acetophenone) Organogels

“…Subsequently, the filtrate was washed with aqueous 5% NaOH and water, separately. After that, solvent was evaporated to obtain the monomer 4-acryloxy acetophenone (AAP) in 55% yield . The 1 H NMR spectrum of the monomer AAP was recorded on a JNM-ECZ600R/S3 spectrometer (JEOL) at 600 MHz.…”

Effective Strategy for Improving the Dielectric Strength and Insulation Lifetime of LLDPE

“…The synthesis of AAP references other literature . Specifically, HAP (0.2 mol) was dissolved in 2-butanone (350 mL) and then triethylamine (TEA, 0.2 mol) was added and stirred in an ice–water bath to keep the reaction temperature at 0–5 °C.…”