Synthesis, characterization, and catalytic applications of Ru(III) complexes containing N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives and triphenylphosphine/triphenylarsine

Ruthenium(II) carbonyl complexes containing ‘pincer like’ ONS donor Schiff base and triphenylphosphine as catalyst for selective oxidation of alcohols at room temperature

“…In these reactions, the catalysts often act via formation of ruthenium-oxo species [26]. In continuation of our research efforts on the development of room temperature catalytic systems for oxidation of alcohols using various transition metal complexes and oxidants [27,28], we disclose herein synthesis, spectroscopy, crystal structure and catalytic oxidation property of ruthenium(II) carbonyl complexes containing ONS donor Schiff base ligand and triphenylphosphine. The ONS donor Schiff base ligands (Fig.…”

Half-sandwich Ru(η6-C6H6) complexes with chiral aroylthioureas for enhanced asymmetric transfer hydrogenation of ketones – experimental and theoretical studies

“…[1][2][3][4][5][6][7][8][9] Half sandwich Ru(II) complexes having η 6 -p-cymene or η 6 -benzene unit are of recent interest due to their superior catalytic activities. [1][2][3][4][5][6][7][8][9] Half sandwich Ru(II) complexes having η 6 -p-cymene or η 6 -benzene unit are of recent interest due to their superior catalytic activities.…”

Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)

“…Thioureas are important organic compounds possessing significant biological activities, act as corrosion inhibitors, catalyst and antioxidant, and are polymer components [1][2][3][4][5][6][7][8][9][10][11][12][13]. Moreover, the hydrogen-bonding ability of the thiourea moiety has been extensively used in the construction of anion receptors.…”