Synthesis, characterization and catalytic evaluation of ZrCl4:Mg(ClO4)2 for the synthesis of 1,3-diaryl-3-(phenylthio)propan-1-one

Atkore, Sandeep T.; Bondle, Giribala M.; Kamble, Vinod T.; Varala, Ravi; Adil, Syed Farooq; Hatshan, Mohammad Rafe; Shaik, Baji

doi:10.1016/j.jscs.2021.101359

Cited by 5 publications

(2 citation statements)

References 47 publications

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“…One of the convenient ways to obtain ketosulfides is the addition of thiols to unsaturated ketones by the Michael reaction. A number of β-ketosulfides were synthesized and characterized by conjugate addition of thiols to α-, β-unsaturated carbonyl compounds in the presence of various catalysts [6][7][8][9][10][11][12][13][14]. Obtaining new representatives of ketosulfides and studying their useful properties is relevant.…”

Section: Introductionmentioning

confidence: 99%

SYNTHESIS OF Β-Ketosulfides BASED ON BENZALACETONE AND RESEARCH INTO THEIR INHIBITORY PROPERTIES

Kyazimov,

Guseynov,

Madji

et al. 2023

Chemical Problems

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The interaction of benzalacetone with mercaptoacetic acid and its alkyl esters was used to synthesize and characterize new representatives of β-ketosulfides, the structure of which was proved by 1H and 13С NMR- spectroscopy. The gravimetric method was used to study the influence of the synthesized compounds on the corrosion rate of St-3 in various aggressive medium. It was established that the studied compounds inhibit the corrosion process both in single-phase acidic (0.1N HCl и 0.1N H2SO4), and in twophase (electrolyte-hydrocarbon) media. In the latter case, they are more effective - the corrosion rate of St-3 decreases from 2.1 to 0.06-0.35 g/m 2 hour, while the degree of protection against corrosion is 83.3-97.1 %. The studied compounds exhibit a greater protective effect in hydrochloric acid solution (97.1-92.45%), than in sulfuric acid (76.9-87.1%). Among the tested compounds, β-ketosulfide obtained on the basis of mercaptoacetic acid showed the highest inhibitory efficiency in both mediums.

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Section: Introductionmentioning

confidence: 99%

SYNTHESIS OF Β-Ketosulfides BASED ON BENZALACETONE AND RESEARCH INTO THEIR INHIBITORY PROPERTIES

Kyazimov,

Guseynov,

Madji

et al. 2023

Chemical Problems

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“…We anticipated that the use of Mg(ClO 4 ) 2 in combination with inexpensive and non-hazardous ZrCl 4 , [37][38][39][40][41][42][43] would be beneficial for the development of novel bimetallic catalyst. In continuation of our efforts in designing novel synthetic strategies for the application in the synthesis bioactive molecules, [44][45][46][47][48] herein, we report a highly efficient acylation of alcohols with acetic acid at room temperature in presence of ZrCl 4 -Mg(ClO 4 ) 2 (Scheme 1).…”

Section: Introductionmentioning

confidence: 99%

ZrCl₄‐Mg(ClO₄)₂: Highly efficient bimetallic catalyst for acetylation of alcohol with acetic acid

Alam

Atkore

Kamble

et al. 2022

Bulletin Korean Chem Soc

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This work describes the highly efficient acetylation (acylation) of alcohols with acetic acid for the ester synthesis in the presence of newly designed a new composite zirconium (IV) chloride and magnesium catalyst which is used bimetallic acidic catalyst ZrCl 4 -Mg(ClO 4 ) 2 , which is formed by grinding ZrCl 4 and Mg(ClO 4 ) 2 in the molar ratio of 1:2, respectively. Thus, the powder X-ray diffraction, scanning electron microscopy, Brunauer-Emmett-Teller surface area, and thermogravimetric analysis of the ZrCl 4 , Mg(ClO 4 ) 2 , and non-calcined ZrCl 4 -Mg (ClO 4 ) 2 were recorded. In each case, structural analysis was carried by grinding the catalyst in mortar and pestle. K E Y W O R D S acylation, bimetallic acidic catalyst, scanning electron microscopy (SEM), substituted alcohol, ZrCl 4 -Mg(ClO 4 ) 2

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Solid polymer electrolyte based on PEO/PVDF/Mg(ClO4)2-[EMIM][ESO4] system for rechargeable magnesium ion batteries

Guzmán-Torres

González-Juárez

Hernández-Nieto

et al. 2023

Ionics

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Synthesis, characterization and catalytic evaluation of ZrCl4:Mg(ClO4)2 for the synthesis of 1,3-diaryl-3-(phenylthio)propan-1-one

Cited by 5 publications

References 47 publications

SYNTHESIS OF Β-Ketosulfides BASED ON BENZALACETONE AND RESEARCH INTO THEIR INHIBITORY PROPERTIES

SYNTHESIS OF Β-Ketosulfides BASED ON BENZALACETONE AND RESEARCH INTO THEIR INHIBITORY PROPERTIES

ZrCl₄‐Mg(ClO₄)₂: Highly efficient bimetallic catalyst for acetylation of alcohol with acetic acid

Solid polymer electrolyte based on PEO/PVDF/Mg(ClO4)2-[EMIM][ESO4] system for rechargeable magnesium ion batteries

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Synthesis, characterization and catalytic evaluation of ZrCl4:Mg(ClO4)2 for the synthesis of 1,3-diaryl-3-(phenylthio)propan-1-one

Cited by 5 publications

References 47 publications

SYNTHESIS OF Β-Ketosulfides BASED ON BENZALACETONE AND RESEARCH INTO THEIR INHIBITORY PROPERTIES

SYNTHESIS OF Β-Ketosulfides BASED ON BENZALACETONE AND RESEARCH INTO THEIR INHIBITORY PROPERTIES

ZrCl4‐Mg(ClO4)2: Highly efficient bimetallic catalyst for acetylation of alcohol with acetic acid

Solid polymer electrolyte based on PEO/PVDF/Mg(ClO4)2-[EMIM][ESO4] system for rechargeable magnesium ion batteries

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ZrCl₄‐Mg(ClO₄)₂: Highly efficient bimetallic catalyst for acetylation of alcohol with acetic acid