Synthesis, characterization, and crystal structure of two zinc(II) halide complexes with the symmetrical bidentate Schiff-base ligand (3,4-MeO-ba)2en

[N,N′-Bis(2,6-dichlorobenzylidene)propane-1,3-diamine-κ2N,N′]dibromidozinc

“…For related structures, see: Khalaj et al (2008Khalaj et al ( , 2009; Salehzadeh et al (2011); Khalaji et al (2010Khalaji et al ( , 2011Khalaji et al ( , 2012. For properties and application of complexes of symmetric bidentate Schiff base ligands, see: Komatsu et al (2007); Montazerozohori et al (2011).…”

“…(Komatsu et al, 2007) and thermal properties (Montazerozohori et al, 2011). There is substantial interest in the coordination chemistry of the zinc(II) ion (Khalaj et al, 2008(Khalaj et al, , 2009Salehzadeh et al,2011;Khalaji et al,2010Khalaji et al, , 2011Khalaji et al, , 2012.…”

Crystal structure, spectroscopic and theoretical studies on two Schiff base compounds of 2,6-dichlorobenzylidene-2,4-dichloroaniline and 2,4-dichlorobenzylidene-2,4-dichloroaniline

“…This compound possesses interesting features like antimicrobial activity, special electrochemical and thermal properties, anionic sensitivity, photochromism and thermochromism, and non-linear optical properties [2][3][4][5]. In continuation of our studies on Schiff base compounds [1][2][3][4], we report the synthesis, characterization and crystal structures of 2,6-dichlorobenzylidene-2,4-dichloroaniline (1) and 2,4-dichlorobenzylidene-2,4-dichloroaniline (2) (see Fig. 1), as well as DFT calculations with B3LYP hybrid functional employing the 6-31G and STO-3G basis sets for all the calculations.…”