2007
DOI: 10.1002/ejic.200600995
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Synthesis, Characterization, and DFT Investigation of IrIII Tolylterpyridine Complexes

Abstract: Three new polypyridine iridium(III) complexes [Ir III Cl(L)-(tterpy)](PF 6 ) 2 {L = phen (1), dpphen (2), and dmbpy (3) (5) and terpy (6)} were also prepared. Abbreviations of the ligands used here are phen = 1,10-phenanthroline, dpphen = 4,7-diphenyl-1,10-phenanthroline, bpy = 2,2Ј-bipyridine, dmbpy = 4,4Ј-dimethyl-2,2Ј-bipyridine, tterpy = 4Ј-(4-tolyl)-2,2Ј:6Ј,2ЈЈ-terpyridine, and terpy = 2,2Ј:6Ј,2ЈЈ-terpyridine. The syntheses, which were accomplished in typical reaction times of fifteen minutes by using a m… Show more

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Cited by 37 publications
(22 citation statements)
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“…The bond angle of the two atoms (N3-Cu-N5) in axial positions is 163.52 (14)°. Therefore, the geometry around the Cu(II) is a distorted octahedron [41][42][43][44].…”
Section: X-ray Structures Of the Complexesmentioning
confidence: 99%
“…The bond angle of the two atoms (N3-Cu-N5) in axial positions is 163.52 (14)°. Therefore, the geometry around the Cu(II) is a distorted octahedron [41][42][43][44].…”
Section: X-ray Structures Of the Complexesmentioning
confidence: 99%
“…The synthesis of related pairs of homoleptic and heteroleptic coplexes containing a {Cr(tpy) 2 [29]. [33]. Each of these metal(III) complexes assembles with the same π-stacked motif shown in Figure 2a [30,34], KAYHIC [35], KEMWEG [36], KUWKOD [37] and QOLYUM [38] …”
Section: Synthesis Of the Chromium(iii) Complexesmentioning
confidence: 99%
“…Recently, we focused on Ir III complexes with terpy, 4Ј-(4-tolyl)-2,2Ј:6Ј,2ЈЈ-terpyridine (tterpy), and/or polypyridine ligands. [17][18][19] These iridium(III) complexes have intense phosphorescences at room temperature and remarkably high quantum yields close to unity. [20] In contrast to the experimental studies, however, theoretical efforts on deep understanding phosphorescent emission seem deficient.…”
Section: Introductionmentioning
confidence: 99%