Synthesis, characterization and electrical properties of Na6M(SO4)4 (M = Co, Ni, Cu) vanthoffite materials

Souamti, Ahmed; Kahlaoui, Massoud; Fezai, Ramzi; Lozano-Gorrı́n, A.D.; Chehimi, Dalila Ben Hassen

doi:10.1016/j.mseb.2019.04.024

Cited by 10 publications

(2 citation statements)

References 49 publications

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“…[ 23,59 ] Unfortunately, only Na 2 VO(SO 4 ) 2 could realize the reversible specific capacity of 60 mAh g −1 at 4.5 V for SIBs. Moreover, the reported Co‐based PSMs, [ 61–63 ] including hydrated [ 38 ] and dehydrated [ 63–65 ] compounds, exhibited no electrochemical activity due to the lack of suitable high‐voltage electrolytes. Based on simulation, many researchers believe that the voltage plateau of Na 2+2 x Co 2− x (SO 4 ) 3 is around 5 V, where most electrolytes might decompose.…”

Section: Psms For Sodium‐ion Batteriesmentioning

confidence: 99%

Low‐Cost Polyanion‐Type Sulfate Cathode for Sodium‐Ion Battery

Gao

Zhang

Liu

et al. 2021

Advanced Energy Materials

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Recently, environmental degradation along with the energy crisis has led to an urgent necessity to develop renewable and clean energy storage devices. The sodium ion batteries (SIBs) have become promising candidates in the whole energy storage system, due to its rich and low‐cost sodium resources. To accelerate the commercialization of SIBs, the energy density of SIBs needs to be further improved. Increasing the operating voltage of SIBs is considered to be an effective method, which requires stable and high‐voltage cathode materials. Comparatively, polyanionic sulfate materials (PSMs) with stable skeletons, adjustable structures, operational safety, and the high electronegativity of SO42− are believed to be the most promising high‐energy‐cathodes. In this review, recent progresses on several typical sulfates for SIBs are summarized. What's more, based on their intrinsic characteristics, the structures and kinetic behaviors of PSMs are also discussed. Reported measures to optimize their electrochemical performances and structural stability are summarized and reviewed. The key challenges and corresponding opportunities for PSMs are also discussed. The insights presented in this review may be a guide for designing and developing stable and practical PSMs for room‐temperature SIBs, which is conducive to promoting their industrialization.

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Section: Psms For Sodium‐ion Batteriesmentioning

confidence: 99%

Low‐Cost Polyanion‐Type Sulfate Cathode for Sodium‐Ion Battery

Gao

Zhang

Liu

et al. 2021

Advanced Energy Materials

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show abstract

“…This can further be utilized in the design of a possible switchable superionic material and can be tested in the sodium-ion battery. 27 We consider the Na 6 M(SO 4 ) 4 crystal structures and performed an initial scan for the energy stability with 3d transition metal cations, M = Mn, Co, Ni and Fe. After carefully considering the energy stability, the M= Mn based system was found to have the lowest electronic energy and was thus selected for further studies.…”

Section: Introductionmentioning

confidence: 99%

Influence of a Temperature Driven Structural Phase Transition on the Ionic Conductivity of Na6Mn(SO4)4 Vanthoffite System

Mazumder¹,

Pati

2022

Preprint

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Sodium Ion Batteries have emerged as practicable successors of the Li-ion battery technology with respect to performance, availability and safety. However, to address the ever-growing demand of improving energy density and capacity, it is important to invest into the research of materials that can serve as efficient battery components and ensure high operational voltages along with long term stability. Polyanionic sulfate materials are known for their high cathodic efficiency owing to their energy densities that arise from electronegativity of sulfate anions. The Vanthoffite class of compounds, with their open framework skeletons, have been explored experimentally as good ionic conductors, which show a temperature dependent ionic conductivity. A superionic phase transition was found in the Mn based system at 445 °C. This structural transition is reversible and is a cumulative effect of the changes in the local topology. Our theoretical calculations provide a mechanistic insight into this phase transition and also establishes Na6Mn(SO4)4 to be an efficient cathode material for sodium ion batteries.

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Enhancing luminescence and dielectric properties in ceramics: rare-earth modification of KMg4(PO4)3-based materials

Souemti,

Selmi,

Martín

et al. 2024

J Mater Sci: Mater Electron

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Synthesis, characterization and electrical properties of Na6M(SO4)4 (M = Co, Ni, Cu) vanthoffite materials

Cited by 10 publications

References 49 publications

Low‐Cost Polyanion‐Type Sulfate Cathode for Sodium‐Ion Battery

Low‐Cost Polyanion‐Type Sulfate Cathode for Sodium‐Ion Battery

Influence of a Temperature Driven Structural Phase Transition on the Ionic Conductivity of Na6Mn(SO4)4 Vanthoffite System

Enhancing luminescence and dielectric properties in ceramics: rare-earth modification of KMg4(PO4)3-based materials

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Synthesis, characterization and electrical properties of Na6M(SO4)4 (M = Co, Ni, Cu) vanthoffite materials

Cited by 10 publications

References 49 publications

Low‐Cost Polyanion‐Type Sulfate Cathode for Sodium‐Ion Battery

Low‐Cost Polyanion‐Type Sulfate Cathode for Sodium‐Ion Battery

Influence of a Temperature Driven Structural Phase Transition on the Ionic Conductivity of Na6Mn(SO4)4 Vanthoffite System

Enhancing luminescence and dielectric properties in ceramics: rare-earth modification of KMg4(PO4)3-based materials

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Product

Resources

About

Synthesis, characterization and electrical properties of Na6M(SO4)4 (M = Co, Ni, Cu) vanthoffite materials