Synthesis, characterization and electrochemical recognition of metal ions of three new ferrocenyl derivatives containing pyridyl moiety

Tian, Hongju; Tang, Ruiren; Li, Shifeng; Luo, Yong

doi:10.1007/s11771-013-1862-7

Cited by 3 publications

(1 citation statement)

References 23 publications

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“…Sensors 48-50 were synthesised by connecting a Fc unit to a pyridyl moiety using a β-diketone bridge [81]. The complexing properties of these sensors towards Zn 2+ , Hg 2+ , Co 2+ , Cu 2+ , Mn 2+ , Cd 2+ and Ni 2+ ions were investigated in ethanol/0.1 M LiClO 4 .…”

Section: Ferrocene-based Electrochemical Sensors Using Nitrogen-conta...mentioning

confidence: 99%

Ferrocene-Based Electrochemical Sensors for Cations

Torriero,

Mruthunjaya

2023

Inorganics

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This study investigates novel ferrocene-based electrochemical sensors for metal cation detection via the design, synthesis and characterisation of ferrocene derivatives. Specifically, this research determines the redox potentials of ferrocene versus decamethylferrocene to provide insight into the redox potential variations. The investigation also examines how electrochemical oxidation of the ferrocene moiety can modulate host affinity for transition metal cations via effects such as electrostatic interactions and changes to coordination chemistry. Metal ion coordination to receptors containing functional groups like imine and quinoline is explored to elucidate selectivity mechanisms. These findings advance the fundamental understanding of ferrocene electrochemistry and host–guest interactions, supporting the development of improved cation sensors with optimised recognition properties, sensitivity and selectivity. Overall, this work lays the necessary groundwork for applications in analytical chemistry and sensor technologies via customised ferrocene-derived materials.

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Section: Ferrocene-based Electrochemical Sensors Using Nitrogen-conta...mentioning

confidence: 99%

Ferrocene-Based Electrochemical Sensors for Cations

Torriero,

Mruthunjaya

2023

Inorganics

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Recent advances in the development of ferrocene based electroactive small molecules for cation recognition: A comprehensive review of the years 2010–2020

Pal

Bhatta

Thakur

2021

Coordination Chemistry Reviews

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Ferrocene-based Electrochemical Sensors for Cations

Torriero,

Mruthunjaya

2023

Preprint

View full text Add to dashboard Cite

This study investigates novel ferrocene-based electrochemical sensors for metal cation detection through the design, synthesis and characterisation of ferrocene derivatives. Specifically, the re-search determines the redox potentials of ferrocene versus decamethylferrocene to provide in-sight into the redox potential variations between them. The investigation also examines how electrochemical oxidation of the ferrocene moiety can modulate host affinity for transition metals cations via effects such as electrostatic interactions and changes to coordination chemistry. Metal ion coordination to receptors containing functional groups like imine and quinoline is explored to elucidate selectivity mechanisms. These findings advance the fundamental understanding of ferrocene electrochemistry and host-guest interactions, supporting the development of improved cation sensors with optimised recognition properties, sensitivity, and selectivity. Overall, the work lays the necessary groundwork for applications in analytical chemistry and sensor technologies through customised ferrocene-derived materials.

show abstract

Synthesis, characterization and electrochemical recognition of metal ions of three new ferrocenyl derivatives containing pyridyl moiety

Cited by 3 publications

References 23 publications

Ferrocene-Based Electrochemical Sensors for Cations

Ferrocene-Based Electrochemical Sensors for Cations

Recent advances in the development of ferrocene based electroactive small molecules for cation recognition: A comprehensive review of the years 2010–2020

Ferrocene-based Electrochemical Sensors for Cations

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