Synthesis, Characterization, and in Vitro Degradation of a Novel Thermotropic Ternary Copolyester Based on p-Hydroxybenzoic Acid, Glycolic Acid, and p-Hydroxycinnamic Acid

Jin, Xiaoming; Carfagna, Cosimo; Nicolais, L.; Lanzetta, Rosa

doi:10.1021/ma00118a001

Cited by 56 publications

(43 citation statements)

References 7 publications

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“…A wide variety of chemical or physical strategies including copolymerization, polymer blend formation and cross-linking network formation have been explored to provide multifunctional polymers [1]. Co-polymerization is one of the existing methods of improving polymer properties.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Co-polymers of N-Phenyl Methacrylamide With Glycidyl Methacrylate

Reddy

et al. 2008

Designed Monomers and Polymers

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Co-polymers of N-phenyl methacrylamide and glycidyl methacrylate of different compositions were synthesized by free radical solution co-polymerization of the monomers in dimethylformamide using benzoyl peroxide as the initiator at 70 • C. Solubility of the co-polymers was tested in various solvents. The molecular structure of the co-polymers was elucidated by infrared and proton nuclear magnetic resonance spectroscopy. The composition of the co-polymers was determined from their 1 H-NMR spectra by using the intensities of aliphatic and aromatic protons present in the co-polymer. The Finemann-Ross and Kelen-Tüdos models have been employed to determine the reactivity ratios of the monomers. The intrinsic viscosities of the co-polymers of GMA and PMA were determined using a Ubblehode viscometer. The thermal transitions of the co-polymers were determined using differential scanning calorimetry and thermogravimetric analysis.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Co-polymers of N-Phenyl Methacrylamide With Glycidyl Methacrylate

Reddy

et al. 2008

Designed Monomers and Polymers

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“…6 A wide variety of chemical or physical strategies including copolymerization, polymer blend formation, and crosslinking network formation have been explored to provide multifunctional polymers. 7 The combination of durability and versatility and the ability to tailor molecules relatively easily to specific applications have made acrylic polymers prime candidates for numerous applications. 8 Acrylate homopolymers along with their copolymers are used in various fields, such as thin films, fibers, filaments, coatings, lithography, lacquers, adhesives, printing inks, binders, and so forth.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of styrene-acrylic ester copolymers

Mathakiya

Rao

Rakshit

2000

J. Appl. Polym. Sci.

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“…chemical or physical strategies including copolyInterest in multifunctional synthetic polymers or merization, polymer blends and composites, or copolymers is steadily increasing, as macromolecucrosslinking networks have been explored to lar catalysts, macromolecular drugs, or antimetamatch the individual requirements. 1 Terpolymerstatic agents. 4 Such activated drug-binding matriizations have continued to evoke interest by both ces are usually based on N-acryloyloxyphthalimide academics and industrialists.…”

Section: Introductionmentioning

confidence: 99%

Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties

Mathakiya

Vangani

Rakshit

1998

J. Appl. Polym. Sci.

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Free-radical solution terpolymerization of acrylamide, acrylic acid, and acrylonitrile was carried out in a mixture of dimethylformamide and water (60 : 40, v/v) at 85ЊC using benzoyl peroxide as the initiator. The polymers were characterized by elemental analysis, IR, 1 H-NMR, TGA, and viscosity measurements. Elemental analysis data were used to evaluate the terpolymer composition. The reactivity ratios were determined by Fineman-Ross and Kelen-Tudos methods. The reactivity ratios (r) for the copolymerization of (1) acrylic acid / acrylonitrile with (2) acrylamide was found to be r 1 Å 0.86 { 0.09 and r 2 Å 1.93 { 0.03, respectively, by the Kelen-Tudos method. The Fineman-Ross method yielded a value of r 1 Å 0.86 { 0.05 and r 2 Å 1.94 { 0.09, respectively. The activation energy values for various stages of decomposition were calculated from TGA analysis. Voluminosity (V E ) and the shape factor (n) were also computed from the viscosity measurements in different ratios of the solvent mixture.

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Synthesis, Characterization, and in Vitro Degradation of a Novel Thermotropic Ternary Copolyester Based on p-Hydroxybenzoic Acid, Glycolic Acid, and p-Hydroxycinnamic Acid

Cited by 56 publications

References 7 publications

Synthesis and Characterization of Co-polymers of N-Phenyl Methacrylamide With Glycidyl Methacrylate

Synthesis and Characterization of Co-polymers of N-Phenyl Methacrylamide With Glycidyl Methacrylate

Synthesis and characterization of styrene-acrylic ester copolymers

Terpolymerization of acrylamide, acrylic acid, and acrylonitrile: Synthesis and properties

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