Synthesis, characterization and magnetic properties of cyanide bridged 1-D metal-coordination polymers based on [Fe^III(s-bqdi)₂(CN)₂]⁻

Abstract

2011) Synthesis, characterization and magnetic properties of cyanide bridged 1-D metal-coordination polymers based on [Fe III (s-bqdi) 2 (CN) 2 ] -, Journal of Coordination Chemistry, 64:5, 805-816, A new series of transition metal complexes K[M II (3), and Cu (4)) have been synthesized. These complexes have been characterized by elemental analyses, FT IR, Far IR, FAB mass, UV-Vis, TGA, CV measurements, and powder XRD. The powder XRD patterns of 2, 3, and 4 show that they are isostructural with hexagonal primitive lattice structures. The coordination polymers display 1-D chain networks. Magnetic properties of the Co II Fe III complex studied by a SQUID magnetometer reveal low-temperature antiferromagnetic interaction.