Synthesis, characterization, and reactivities of high valent metal–corrole (M = Cr, Mn, and Fe) complexes

Corroles and Hexaphyrins: Synthesis and Application in Cancer Photodynamic Therapy

“…In recent decades, the synthesis of corroles and metallocorroles had attracted considerable attention from the scientific community and some reviews have been published [ 4 , 6 , 7 , 9 , 33 , 34 ]. Nevertheless, the relevance of corroles’ applications has driven the development of interesting approaches to construct macrocycles with new moieties, via classical and novel methodologies, collected herein.…”

Oxo(corrolato)vanadium(iv) catalyzed epoxidation: oxo(peroxo)(corrolato)vanadium(v) is the true catalytic species

“…Corrole, a contracted porphyrin analog, is known to stabilize metals in a higher oxidation state. [30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49] Corrole has excellent chelating properties; many metal complexes across the periodic table bearing corrole ligand functionalities have already been reported in the literature. [50][51][52][53][54][55][56][57][58][59][60][61][62][63] Licoccia et al first synthesized oxo(corrolato)vanadium(IV) complexes bearing b-substitution at the corrole periphery.…”

Photocatalytic C–H Thiocyanation of Corroles: Development of Near-Infrared (NIR)-Emissive Dyes

“…Corrole, a contracted version of porphyrin having 18 π-electrons has many similarities with porphyrins . The spectroscopic properties of corroles are similar to those of porphyrin in many aspects. − The triplet state lifetime of corroles is in the range of 10 –4 to 10 –5 s . Similar to porphyrin, corroles also act as a photosensitizer. , Although there are few examples of porphyrin in photoredox catalysis, similar studies in corroles are still rare.…”