Synthesis, Characterization, and Structural Investigations of 1‐Amino‐3‐substituted‐1,2,3‐triazolium Salts, and a New Route to 1‐Substituted‐1,2,3‐triazoles.

Kaplan, Greg; Drake, Greg; Tollison, Kerri; Hall, Leslie; Hawkins, Tommy

doi:10.1002/chin.200527130

Cited by 2 publications

(2 citation statements)

References 38 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…MeOHAN was prepared from commercially available methoxy-ammonium chloride (Aldrich), 2H-Tetrazole-5-[(1,1-dimethylhydrazinium) methyl] nitrate was synthezised for the first time for this investigation (supporting information (S3)). 1-Amino-1,2,3-triazole and 4-amino-1,2,4-trizolium nitrate were prepared according to literature procedures [11,12].…”

Section: Methodsmentioning

confidence: 99%

Solid+Solid=Liquid: An ON‐Switch for Sensitivity in Deep Eutectic Solvents?

Ahmed

Quintana

Warmoth

et al. 2019

Propellants Explo Pyrotec

View full text Add to dashboard Cite

Deep Eutectic Solvents show the low volatility/toxicity of “classical” Ionic Liquids. The formation of a Deep Eutectic Solvent from two solids is the result of intermolecular bonds being weakened or broken and rearranged in completely new networks. The effect of these new bonding arrangements on physical properties like melting point, thermal stability, density, viscosity, and impact sensitivity of some binary mixtures of energetic nitrate salt and nitrogen containing ligands was investigated. With some exceptions the liquids showed increased sensitivity compared to their solid ingredients, which suggest that this might provide an ON‐switch for sensitivity. Furthermore, applying the Deep Eutectic Solvent concept to propellant and explosive development may allow incorporation of established energetic solids into liquid applications.

show abstract

Section: Methodsmentioning

confidence: 99%

Solid+Solid=Liquid: An ON‐Switch for Sensitivity in Deep Eutectic Solvents?

Ahmed

Quintana

Warmoth

et al. 2019

Propellants Explo Pyrotec

View full text Add to dashboard Cite

show abstract

“…The organic nitrogen-containing heterocycle fragments, such as pyrazole-, imidazole-, triazole-, tetrazole-and pentazole-moieties, can be either cationic or anionic in nitrogen rich energetic salts [12][13][14][15][16][17][18][19][20]. Among these energetic ions, the tetrazolium (positively charged tetrazole) or tetrazolide (negatively charged tetrazole) rings (see Figure 1) furnish an important area of chemistry because of the practical and theoretical significance of these unique compounds and because they tend to have a reduced environmental impact [21].…”

Section: Introductionmentioning

confidence: 99%