Synthesis, crystal structure and electrochemical properties of a novel tetranuclear silver(I) cluster based on 1,1′-bis[(2-hydroxybenzylidene)thiocarbonohydrazono-1-ethyl] ferrocene (FcL)

Qiao, Chunjie; Ding, De‐Gang; Li, Jie; Gu, Lin; Xu, Yan; Fan, Yaoting

doi:10.1016/j.inoche.2009.08.020

Cited by 4 publications

(3 citation statements)

References 21 publications

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“…Selected bond lengths and angles for these structures are collected in Tables S5–S9. In all cases, the bond distances M–S, M–N, and M–P (M = Cu I , Ag I , and Au I ) are in the range expected for complexes derived from thiocarbohydrazone ligands. , …”

Section: Resultsmentioning

confidence: 73%

“…In all cases, the bond distances M–S, M–N, and M–P (M = Cu I , Ag I , and Au I ) are in the range expected for complexes derived from thiocarbohydrazone ligands. 37 , 39 …”

Section: Resultsmentioning

confidence: 99%

“…Among them, grids , and mononuclear and dinuclear species have been described. Also, examples of silver(I) clusters derived from these types of ligands have been found. , In addition, no examples of donor NSP-thiocarbohydrazone ligands have been found in the literature.…”

Section: Introductionmentioning

confidence: 99%

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Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis

et al. 2022

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We report two different approaches to isolate neutral and cationic mesocate-type metallosupramolecular architectures derived from coinage monovalent ions. For this purpose, we use a thiocarbohydrazone ligand, H 2 L ( 1 ), conveniently tuned with bulky phosphine groups to stabilize the M I ions and prevent ligand crossing to achieve the selective formation of mesocates. The neutral complexes [Cu 2 (HL) 2 ] ( 2 ), [Ag 2 (HL) 2 ] ( 3 ), and [Au 2 (HL) 2 ] ( 4 ) were prepared by an electrochemical method, while the cationic complexes [Cu 2 (H 2 L) 2 ](PF 6 ) 2 ( 5 ), [Cu 2 (H 2 L) 2 ](BF 4 ) 2 ( 6 ), [Ag 2 (H 2 L) 2 ](PF 6 ) 2 ( 7 ), [Ag 4 (HL) 2 ](NO 3 ) 2 ( 8 ), and [Au 2 (H 2 L) 2 ]Cl 2 ( 9 ) were obtained by using a metal salt as the precursor. All of the complexes are neutral or cationic dinuclear mesocates, except the silver nitrate derivative, which exhibits a tetranuclear cluster mesocate architecture. The crystal structures of the neutral and cationic copper(I), silver(I), and gold(I) complexes allow us to analyze the influence of synthetic methodology or the counterion role on both the micro- and macrostructures of the mesocates.

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Section: Resultsmentioning

confidence: 73%

“…In all cases, the bond distances M–S, M–N, and M–P (M = Cu I , Ag I , and Au I ) are in the range expected for complexes derived from thiocarbohydrazone ligands. 37 , 39 …”

Section: Resultsmentioning

confidence: 99%

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Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis

et al. 2022

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On the Reactivity of Thiourea Derivatives with Silver(I) Oxide

Pilz

Mohr

2020

Eur J Inorg Chem

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Aryl thioureas of the type ArNHC(S)NR2 react with Ag2O to form the corresponding silver(I) thioureato complexes. Depending on the nature of the thiourea, either insoluble materials, zig‐zag coordination polymers or discrete tetranuclear silver species were isolated and structurally characterised. These thioureato complexes react with one, two or three equivalents of a phosphine ligand, forming a series of compounds with various structural motifs and different coordination numbers at the metal. The spectroscopic properties and structures of several of these compounds are discussed.

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A multiprotic indole-based thiocarbohydrazone in the formation of mono-, di- and hexa-nuclear metal complexes

2014

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Synthesis, crystal structure and electrochemical properties of a novel tetranuclear silver(I) cluster based on 1,1′-bis[(2-hydroxybenzylidene)thiocarbonohydrazono-1-ethyl] ferrocene (FcL)

Cited by 4 publications

References 21 publications

Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis

Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis

On the Reactivity of Thiourea Derivatives with Silver(I) Oxide

A multiprotic indole-based thiocarbohydrazone in the formation of mono-, di- and hexa-nuclear metal complexes

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