“…In recent years, many efforts have been devoted to the preparation and characterization of spiro compounds due to diverse industrial and biomedical applications in medicine [1][2][3], catalysis [4], 18F-radiolabeling [5] and optical material [6][7][8]. The asymmetric characteristic of the molecules, owing to the chiral spiro carbon, is one of the important criteria of the biological activities.…”
Abstract:Two new oxaspirocyclic compounds, 8-(4-(dimethylamino)benzylidene)-6,10-dioxaspiro [4.5] decane-7,9-dione (1) and 8-(4-hydroxybenzylidene)-6,10-dioxaspiro[4.5]decane-7,9-dione (2) have been synthesized and their structures determined by single crystal X-ray crystallography. Compound 1, C 17 H 19 NO 4 , belongs to the monoclinic system, space group P21/c with a = 6.2554 (13)
“…In recent years, many efforts have been devoted to the preparation and characterization of spiro compounds due to diverse industrial and biomedical applications in medicine [1][2][3], catalysis [4], 18F-radiolabeling [5] and optical material [6][7][8]. The asymmetric characteristic of the molecules, owing to the chiral spiro carbon, is one of the important criteria of the biological activities.…”
Abstract:Two new oxaspirocyclic compounds, 8-(4-(dimethylamino)benzylidene)-6,10-dioxaspiro [4.5] decane-7,9-dione (1) and 8-(4-hydroxybenzylidene)-6,10-dioxaspiro[4.5]decane-7,9-dione (2) have been synthesized and their structures determined by single crystal X-ray crystallography. Compound 1, C 17 H 19 NO 4 , belongs to the monoclinic system, space group P21/c with a = 6.2554 (13)
“…The role of the long alkyl chain is to passivate the TiO 2 surface so that the electrons are screened from reaching the oxidized cobalt ions, thus suppressing the back electron transfer by charge recombination. [32][33][34][35]…”
Bifacial solar cells (BFSCs) are gaining popularity due to their compactness, space‐saving property, and higher photoconversion efficiency (PCE) than mono‐facial solar cells. Bifacial dye‐sensitized solar cells (BF‐DSSCs) are fabricated and characterized utilizing D‐205 as a dye‐sensitizer in combination with I‐/I3
‐ and Co2+/Co3+ redox electrolytes. BF‐DSSCs using iodine‐based electrolytes demonstrate a cumulative PCE and bifaciality factor (BFF) of 13.05% and 85%, respectively. The hampered PCE under back‐side light illumination is attributed to the absorption of photons by the electrolyte itself. Contrary to this, BF‐DSSCs fabricated using cobalt‐complex‐based redox electrolyte exhibits an exceptionally high BFF of nearly 100% with a PCE of 4.77% and 4.75% under the front and rear light illumination, respectively. Although the open circuit voltage (Voc) of the BF‐DSSCs fabricated using cobalt electrolyte (with deeper redox potential) is slightly higher than that of BF‐DSSCs fabricated using iodine electrolyte, their cumulative PCE (9.52%) is much lower than that of iodine‐based device counterparts (13.05%). This decrease in PCE is attributed to the relatively fast charge recombination in the cobalt electrolyte‐based BF‐DSSCs.This article is protected by copyright. All rights reserved.
“…With the advantages of unique pharmacological activity [4,5], high catalytic activity [6], photoelectric properties [7], biological activity [8], simple operation and low cost, pyridine derivatives were widely used in the areas of pharmacy and chemical industry [9,10]. Obviously, the synthesis of new pyridine derivatives have drawn attentions in recent decades.…”
C30H23NO2, orthorhombic, Pbca (no. 61), a = 10.7674(16) Å, b = 19.542(3) Å, c = 20.970(3) Å, V = 4412.5(11) Å3, Z = 8, Rgt(F) = 0.0350, wRref(F2) = 0.0963, T = 153 K.
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