Synthesis, crystal structure, and properties of supramolecular CuII, ZnII, and CdII complexes with Salen-type bisoxime ligands

Crystal structure of (E)-1-(2-chlorophenyl)-N-(4-chlorophenyl)methanimine, C13H9Cl2N

“…Schi -bases have been of great interest for many years because of their wide application in metal coordination chemistry as important classes of ligands and higher bioactivity [1][2][3][4][5][6][7][8][9][10][11][12][13][14]. In order to search for new Schi -bases, the title compound was synthesized and its crystal structure determined.…”

Crystal structure of 2-((E)-(6-methylpyridin-2-ylimino)methyl)-4- methylphenol, C14H14N2O

“…The Schiff base compounds and their derivatives have been playing an important role in the development of coordination chemistry [1,2] because these compounds can accommodate one, two or more metal centers and formh omo-and heteronuclear metal complexes with interesting properties [3][4][5][6], such as excellent catalytic activities for epoxidation, aziridination, etc. [7], models of reaction centersofmetalloenzymes [8],and nonlinearoptical materials [9].Here we designed and synthesized anew Schiff base named2 -((E)-(6-methylpyridin-2-ylimino)methyl)-4-methylphenol.…”

Crystal structure of 2,2'-(1,2-ethylenedioxy)bisbenzaldehyde O,O'-dimethyldioxime, C18H20N2O4

“…These compounds can accommodate one, two or more metal centers and form homo-and heteronuclear metal complexes serving as catalysts [ 7], models of reaction centers of metalloenzymes [8], nonlinear optical materials [9] and molecular recognition and biological agents [10].…”