2011
DOI: 10.1016/j.crci.2010.12.002
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Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4’-dimethyl-2,2’-bipyridine and azide

Abstract: Full paper/Me ´moire Synthesis, crystal structure and thermal decomposition of Cu(II), Co(II), Mn(II) complexes with hetero-ligands containing cysteic acid, 4,4'-dimethyl-2,2'-bipyridine and azide

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Cited by 15 publications
(5 citation statements)
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“…This situation has generated much interest. [34][35][36] Bipyridines in metal complexes that have M-N distances within the typical range (ca. 2.0-2.2 Å) are not planar.…”
Section: Structural Resultsmentioning
confidence: 99%
“…This situation has generated much interest. [34][35][36] Bipyridines in metal complexes that have M-N distances within the typical range (ca. 2.0-2.2 Å) are not planar.…”
Section: Structural Resultsmentioning
confidence: 99%
“…Two different ligands were in addition chosen: 5,5′‐ and 4,4′‐substituted 2,2′‐bipyridines, expected to display relatively minor structural differences of the different complexes compared to the 3,3′‐ or 6,6′‐substituted counterparts . Crystal structures have been reported for some of the homoleptic complexes . For detection purposes, 5,5′‐dimethyl‐2,2′‐bipyridine L1 and stable, isotope‐labeled ligand [D 6 ]‐4,4′‐dimethyl‐2,2′‐bipyridine L2 , prepared using microwave‐assisted deuteration, were thus used to construct the complexes (Figure ).…”
Section: Resultsmentioning
confidence: 99%
“…The popularity of such aromatic carboxylic acids as building blocks for generating metalorganic architectures can be explained by their coordination versatility and ability to act as multiple linkers (Lehleh et al, 2015;Gu et al, 2020), high thermal stability, tuneable deprotonation of -COOH groups, remarkable physicochemical properties, as well as the ability to function as hydrogen-bond donors and acceptors, thus facilitating the formation of intricate hydrogen-bonded networks (Gu et al, 2020;Zhang et al, 2019;Zhou et al, 2019). Furthermore, bipyridyl-like ligands such as 2,2 0 -bipyridine and 1,10-phenanthroline used as auxiliary ligands, are usually used in the formation of different complexes with a variety of transition metals, because of their versatile roles such as in analytical chemistry, in catalysis, in electrochemistry, in ring-opening metathesis polymerization and biochemistry (Lehleh et al, 2011). Additionally, the pyridine rings can not only interact with each other viastacking interactions, but also act as hydrogen-bond donors and acceptors (Cao et al, 2014;Hao et al, 2011;Lehleh et al, 2011).…”
Section: Chemical Contextmentioning
confidence: 99%
“…Furthermore, bipyridyl-like ligands such as 2,2 0 -bipyridine and 1,10-phenanthroline used as auxiliary ligands, are usually used in the formation of different complexes with a variety of transition metals, because of their versatile roles such as in analytical chemistry, in catalysis, in electrochemistry, in ring-opening metathesis polymerization and biochemistry (Lehleh et al, 2011). Additionally, the pyridine rings can not only interact with each other viastacking interactions, but also act as hydrogen-bond donors and acceptors (Cao et al, 2014;Hao et al, 2011;Lehleh et al, 2011).…”
Section: Chemical Contextmentioning
confidence: 99%